[Mn(2,2'-bipyridine)(CO)3]- | 156189-62-7

• 英文名称: [Mn(2,2'-bipyridine)(CO)3]-
• 英文别名: [(2,2′-bipyridine)Mn(CO)₃]^-；[Mn(2,2'-bipyridine)(CO)₃]⁻；[Mn(CO)₃(2,2’-bipyridine)]^-；[Mn(2,2'-bipyridine)(CO)₃]^-；[Mn(bpy)(CO)₃]⁻；[Mn(CO)₃(bipy)]^-；[Mn(2,2′-bipyridine)(CO)3](1-)
• CAS: 156189-62-7
• 化学式: C₁₃H₈MnN₂O₃
• 分子量: 295.156
• InChiKey: RMIDENKFUBAMOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Mn(bpy)(CO)₃Br 以 乙腈 为溶剂， 生成 [Mn(2,2'-bipyridine)(CO)3]-
  参考文献：
  名称：

  [Mn（联吡啶基）（CO）3Br]：丰富的金属羰基配合物，可作为高效的CO2还原电催化剂

  摘要：

  工作中的锰：事实证明，基于锰的羰基联吡啶基络合物是一种贵重，廉价的非贵金属，是在温和条件下将CO 2选择性电化学还原为CO的出色分子催化剂。锰配合物优于rh配合物的另一个优点是这些催化剂的过电势明显更低（0.40 V增益）。

  DOI：

  10.1002/anie.201103616

文献信息

• Selective Catalytic Electroreduction of CO₂ at Silicon Nanowires (SiNWs) Photocathodes Using Non-Noble Metal-Based Manganese Carbonyl Bipyridyl Molecular Catalysts in Solution and Grafted onto SiNWs
  作者：Encarnación Torralba-Peñalver、Yun Luo、Jean-Daniel Compain、Sylvie Chardon-Noblat、Bruno Fabre

  DOI：10.1021/acscatal.5b01546

  日期：2015.10.2

  The electrocatalytic reduction of CO2 to CO in hydroorganic medium has been investigated at illuminated (lambda > 600 nm; 20 mW cm(-2)) hydrogen-terminated silicon nanowires (SiNWs-H) photocathodes using three Mn-based carbonyl bipyridyl complexes as homogeneous molecular catalysts ([Mn(L) (CO)(3)(CH3CN)](PF6) and [Mn(bpy) (CO)(3)Br) with L = bpy = 2,2'-bipyridine and dmbpy = 4,4'-dimethyl-2,2'-bipyridine). Systematic comparison of their cyclic voltammetry characteristics with those obtained at flat hydrogen-terminated silicon and traditional glassy carbon electrodes (GCE) enabled us to demonstrate the superior catalytic efficiency of SiNWs-H in terms of cathodic photocurrent densities and overpotentials. For example, the photocurrent densities measured at -1.0 V vs SCE for [Mn(bpy) (CO)(3)(CH3CN)](PF6) at SiNWs-H exceeded 1.0 mA cm(-2) in CO2-saturated CH3CN + 5% v/v H2O, whereas almost zero current was measured at this potential at GCE. Such characteristics have been supported by the energetic diagrams built for the different SiNWs vertical bar Mn-based catalyst interfaces. The fill factor FF and energy conversion efficiency eta calculated under catalytic conditions were higher for [Mn(bpy or dmbpy) (CO)(3)(CH3CN)](PF6) (FF = 0.35 and 0.34; eta = 3.0 and 2.0%, respectively). Further preparative-scale electrolysis at SiNWs-H photocathode with Mn-based complex catalysts in electrolytic solution evidenced the quantitative conversion of CO2 to CO with a higher stability of the [Mn(dmbpy) (CO)(3)(CH3CN)](PF6) complex. Finally, in order to develop technologically viable electrocatalytic devices, the elaboration of SiNWs-H photoelectrodes modified with a Mn-based complex has been successfully achieved from an electropolymerizable catalyst, and it was shown that the electrocatalytic activity of the complex was retained after immobilization.