catena-poly[copper(I)-μ-hexakis(methylthio)benzene-S(1),S(2):S(4),S(5)] hexafluorophosphate | 219691-85-7

• 英文名称: catena-poly[copper(I)-μ-hexakis(methylthio)benzene-S(1),S(2):S(4),S(5)] hexafluorophosphate
• CAS: 219691-85-7
• 化学式: C₁₂H₁₈S₆*Cu*F₆P
• 分子量: 563.181
• InChiKey: GJHIRKXTOALZBZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrakis(acetonitrile)copper(I) hexafluorophosphate 、 六(甲硫基)苯 以 丙酮 为溶剂， 生成 catena-poly[copper(I)-μ-hexakis(methylthio)benzene-S(1),S(2):S(4),S(5)] hexafluorophosphate
  参考文献：
  名称：

  Syntheses and structures of copper(I) and silver(I) coordination polymers with hexakis(methylthio)benzene

  摘要：

  DOI：

  10.1016/s0277-5387(98)00314-3

文献信息

• A Linear-Chain Copper(I) Coordination Polymer with Hexakis(methylthio)benzene
  作者：Y. Suenaga、T. Kuroda-Sowa、M. Munakata、M. Maekawa、H. Morimoto

  DOI：10.1107/s010827019800643x

  日期：1998.11.15

  In the structure of catena-poly [copper(I)-mu-[hexakis(methylthio)benzene-S-1,S-2:S-4,S-5]] hexafluorophosphate, [Cu(C12H18S6)]PF6}(n), each Cu atom is coordinated to four S atoms of two hexakis(methylthio)benzene ligands in a tetrahedral arrangement to give a cationic linear-chain polymer. The electrical resistivity of compacted pellets was measured by the conventional two-probe technique. Iodine-doped black products in powder form behave as a semiconductor with a conductivity of 1.5 x 10(-6) S cm(-1).