[N(n-butyl)4]trans-[RuCl4(dimethylsulfoxide)(4,4'-bipyridine)] | 952093-51-5

• 英文名称: [N(n-butyl)4]trans-[RuCl4(dimethylsulfoxide)(4,4'-bipyridine)]
• CAS: 952093-51-5
• 化学式: C₁₂H₁₄Cl₄N₂ORuS*C₁₆H₃₆N
• 分子量: 719.673
• InChiKey: PIHQBRLMDTVADH-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  4,4'-联吡啶 、 [nBu4N][trans-RuCl4(dimethyl sulfoxide)2] 以 丙酮 为溶剂， 以86%的产率得到[N(n-butyl)4]trans-[RuCl4(dimethylsulfoxide)(4,4'-bipyridine)]
  参考文献：
  名称：

  Synthesis and characterization of ionic Ru(III) complexes containing dimethylsulfoxide and dinitrogen heterocyclic ligands

  摘要：

  Several new Ru(III) DMSO compounds including [PPh4]trans-[Ru(DMSO)(2)Cl-4], [PPh4]trans-[Ru(DMSO)(pyrazine)Cl-4] (2), [PPh4]trans-[Ru(DMSO)(4,4'-bipyridine)Cl-4] and [PPh4]trans-[Ru(DMSO)(pyrimidine)Cl-4] were reported and characterized. The crystal structure of 2 and its Na+ analogue were determined by X-ray diffraction methods. The PPh4+ complex 2 is a discrete ionic compound, while the compound [Na]trans-[Ru(DMSO)(pyrazine)Cl-4]center dot DMSO (3) crystallized with a molecule of DMSO. The environment around the Na atom is a distorted octahedron with short contacts with three chloro ligands, two O atoms from the bonded and unbonded DMSO molecules, and the unbonded N atom of the pyrazine ligand. The Na atoms form bridges between the complexed anions in 3 resulting in the formation of infinite chains or ribbons parallel to the b axis. The chains are held together by van der Waals interactions. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.03.041