Acetic acid (2R,3R,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-6-methoxy-5-((2S,3R,4S,5S,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester | 82430-50-0

• 英文名称: Acetic acid (2R,3R,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-6-methoxy-5-((2S,3R,4S,5S,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester
• CAS: 82430-50-0
• 化学式: C₂₇H₃₈O₁₈
• 分子量: 650.588
• InChiKey: SWVBBYOXGRDAEU-INRNKMSJSA-N

反应信息

• 作为反应物：
  描述：

  Acetic acid (2R,3R,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-6-methoxy-5-((2S,3R,4S,5S,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester 在 硫酸 、 sodium methylate 作用下， 反应 48.0h， 生成 O-β-D-mannopyranosyl-(1->2)-D-mannopyranose
  参考文献：
  名称：

  Temeriusz, Andrzej; Piekarska, Boguslawa; Stepinski, Janusz, Polish Journal of Chemistry, 1981, vol. 55, # 4, p. 783 - 791

  摘要：

  DOI：