[W(CO)5{PPh2(C2Ph)}] | 91946-77-9

• 英文名称: [W(CO)5{PPh2(C2Ph)}]
• 英文别名: [W(CO)₅{PPh₂(C₂Ph)}]
• CAS: 91946-77-9
• 化学式: C₂₅H₁₅O₅PW
• 分子量: 610.215
• InChiKey: MGRZSJUBRCRAGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [W(CO)5{P(phenyl)2Cl}] 以 二氯甲烷 为溶剂， 反应 2.17h， 生成 [W(CO)5{PPh2(C2Ph)}]
  参考文献：
  名称：

  钨的二苯基phosph和三氟甲磺酸二苯基膦配合物的磷-碳键形成反应

  摘要：

  The complex [W(CO)(5){PClPh2}] reacts with AlCl3 to form a mixture of the phosphenium complex [W(CO)(5){PPh2}][AlCl4] and an isocarbonyl, with GaCl3 to form [W(CO)(5){PPh2}][GaCl4], and with silver trifluoromethanesulfonate to form [W(CO)(5){P(OSO2CF3)Ph-2}]. All three complexes react as strong P electrophiles, undergoing electrophilic substitution reactions with aromatic and heteroaromatic compounds, alkenes, and alkynes, to form aromatic and heteroaromatic phosphines, allyl phosphines, and alkynyl phosphines, respectively. Alkenes lacking cleavable gamma-H atoms and internal alkynes undergo tandem electrophilic addition/substitution reactions, adding between the P and one of the phenyl rings to form fused P heterocycles. The newly formed phosphines can be removed from the tungsten complex by photolysis in the presence of bis(diphenylphosphino)ethane.

  DOI：

  10.1021/acs.organomet.6b00348

文献信息

• Alkinylphosphinhaltige substitutionsprodukte von chrom- und wolfram-hexacarbonyl
  作者：A Hengefeld、R Nast

  DOI：10.1016/0022-328x(84)80170-9

  日期：1984.5

  The photochemical preparation of [M(CO)5(P(CCC6H5)n(C6H5)3-n], cis-[M(CO)4(PCCC6H5)n(C6H5)3-n] (M = Cr, W; n = 1,2,3) and fac-[Cr(CO)3(P(CCC6H5)(C6H5)3] by the corresponding substitution reactions of the hexacarbonyls is described. The IR and Raman spectra of the complexes in the region of the ν(CO) and ν(CC) vibrations and the 31P NMR spectra are discussed.

  的光化学制备[M（CO）5（P（CCC 6 ħ 5）Ñ（C 6 H ^ 5）3- Ñ ]，顺式- [M（CO）4（PCCC 6 ħ 5）Ñ（ ç 6 ħ 5）3- ñ ]（M =铬，W; ñ = 1,2,3）和FAC - [CR（CO）3（P（CCC 6 ħ 5）（C 6 H ^ 5）3描述了通过六羰基的相应取代反应。讨论了在ν（CO）和ν（CC）振动区域内配合物的IR和拉曼光谱以及31 P NMR光谱。