| 1304045-06-4

• CAS: 1304045-06-4
• 化学式: C₃₁H₅₁ClNP₂Rh
• 分子量: 638.059
• InChiKey: NYKNUNSPJWHKMF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  7,8-苯并喹啉 、 chloro(1,5-cyclooctadiene)rhodium(I) dimer 以 四氢呋喃 为溶剂， 以76.3%的产率得到
  参考文献：
  名称：

  Aliphatic and aromatic C–H activation of benzo[h]quinolines by Rh(I). Unique precursor dependent formation of mono-, di- and trinuclear complexes

  摘要：

  Treatment of 7,8-benzo[h] quinoline (bhq-H, 1) and 10-methyl benzo[h] quinoline (bhq-Me, 3) with [Rh(C2H4)(2)(THF)(2)][BF4] resulted in double C-H activation of aliphatic and aromatic C-H bonds, yielding the Rh(III) complexes 4 and 5, respectively. The structures of 4 and 5 were revealed by X-ray diffraction. The reaction of 1 with two other slightly different rhodium precursors, [Rh(olefin)(n)(THF)(2)][BF4] (COE (n = 2), COD (n = 1)), led to completely different products, a dinuclear complex 7 and a trinuclear complex 6, respectively, which were characterized by X-ray diffraction. Complex 6 exhibits a rare linear Rh-Rh-Rh structure. Utilizing excess of 1 with [Rh(COD)(THF)(2)][BF4] led to the formation of a new product 8 with no C-H bond activation taking place. Additional C-H activation products of 1, cationic and neutral, in the presence of PiPr(3) (9a, 9b and 10) are also presented. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.12.064