methoxy(phenyl)methyl-o-carborane | 257889-10-4

• 英文名称: methoxy(phenyl)methyl-o-carborane
• 英文别名: methoxy(phenyl)-o-carborane
• CAS: 257889-10-4；257889-17-1
• 化学式: C₁₀H₂₀B₁₀O
• 分子量: 264.378
• InChiKey: INCSCPQQGGTNIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  methoxy(phenyl)methyl-o-carborane 、 二甲基溴化锡 在 n-butyllithium 作用下， 以 乙醚 为溶剂， 以83%的产率得到[methoxy(phenyl)methyl-o-carboranyl]SnMe2Br
  参考文献：
  名称：

  Chiral organotin complexes stabilized by C,N-chelating oxazolinyl-o-carboranes

  摘要：

  A series of chiral organotin halides containing 2-(4-R)-oxazolinyl-o-carboranes (R = i-propyl 1, t-butyl 2; Cab(Oxa)) was prepared from o-carborane with a chiral oxazoline auxiliary. X-ray structural analysis of the representative chiral organotin halide, [2-(4-i-propyl)-oxazolinyl-o-carboranyl]SnMe(2)Br (4), revealed the formation of a stable penta-coordinated tin center due to a N -> Sn interaction. Similar O -> Sn assisted intramolecular penta-coordinated tin complexes (9 and 10) were prepared from methoxy-o-carborane ligands, MeOCH(Z)-o-carborane (Z = H 7, Ph 8; Cab(OMe)), respectively, and a rigid o-carboranyl backbone provided the basic skeleton for the facile formation of organotin complexes. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.10.030
• 作为产物：
  描述：

  1-(o-carboranyl)benzyl alcohol 、 碘甲烷 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 以90%的产率得到methoxy(phenyl)methyl-o-carborane
  参考文献：
  名称：

  Chiral organotin complexes stabilized by C,N-chelating oxazolinyl-o-carboranes

  摘要：

  A series of chiral organotin halides containing 2-(4-R)-oxazolinyl-o-carboranes (R = i-propyl 1, t-butyl 2; Cab(Oxa)) was prepared from o-carborane with a chiral oxazoline auxiliary. X-ray structural analysis of the representative chiral organotin halide, [2-(4-i-propyl)-oxazolinyl-o-carboranyl]SnMe(2)Br (4), revealed the formation of a stable penta-coordinated tin center due to a N -> Sn interaction. Similar O -> Sn assisted intramolecular penta-coordinated tin complexes (9 and 10) were prepared from methoxy-o-carborane ligands, MeOCH(Z)-o-carborane (Z = H 7, Ph 8; Cab(OMe)), respectively, and a rigid o-carboranyl backbone provided the basic skeleton for the facile formation of organotin complexes. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.10.030