| 106049-22-3

• CAS: 106049-22-3
• 化学式: C₁₃H₂₅ClP₂Pd
• 分子量: 385.162
• InChiKey: UWRCRSGXMAJNKS-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  异氰酸叔丁酯 、 以 四氢呋喃 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  Observation of a Non-H-Bond-Stabilized Tautomeric Imine-Enamine Equilibrium in Iminoacyl-Palladium Complexes

  摘要：

  Iminoacyl complexes of the type trans-Pd-(C(=NBu(t))(CH2C6H4-p-X))Cl(PR(3))(2) exist in solution as equilibrium mixtures of their imine and enamine forms. The position of the equilibria can, be tuned by varying the X substituent of the aryl ring and the phosphine ligands, allowing in some cases the isolation of compounds that exist as the less common enamine form, both in solution and in, the solid state.

  DOI：

  10.1021/om00005a009