| 154648-25-6

• CAS: 154648-25-6
• 化学式: C₅₀H₄₃FeHgI₂N₄P
• 分子量: 1241.14
• InChiKey: RMGDZCNBOWMWTC-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  汞 、 在 三苯基膦 作用下， 以 四氢呋喃 为溶剂， 以58%的产率得到
  参考文献：
  名称：

  Insertion of mercury into iron-iodine bonds leading to dinuclear (FeHg) mixed isonitrile-phosphine complexes

  摘要：

  The binuclear complexes trans-[Fe(Hg(I)2)(PPh(3))(CNR)(4)](R = Ph, 4-MeC(6)H(4), or (t)Bu), trans-[Fe(HgI2)(dppm-P)(CNR)(4)] (R = Ph or 4-MeC(6)H(4)), and mer-[Fe(HgI2)(dppe)(CNR)(3)] (R = Ph or 4-MeC(6)H(4)) were obtained by the reaction of metallic mercury with [FeI2(CNR)(6)] in the presence of phosphines such as PPh(3), Ph(2)PCH(2)PPh(2) (dppm) and Ph(2)PCH(2)CH(2)PPh(2) (dppe); this process yields adducts of the Lewis acid HgI2 with the metallic bases ''FeL(CNR)(4)'' (L= PPh(3) or dppmp) or ''Fe(dppe)(CNR)(3)''. Spectroscopic data and conductivity measurements suggest a sequence for the strength of these metallic fragments acting as bases.

  DOI：

  10.1016/0022-328x(94)87276-7