| 1103533-90-9

• CAS: 1103533-90-9
• 化学式: C₂₅H₃₃ClNPRu
• 分子量: 515.04
• InChiKey: BSQMUFSECYJXQO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Cp*RuCl(isoprene) 、 2-(diphenylphosphino)-N-methylethanamine 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  A Convenient Method for the Synthesis of Protic 2-(Tertiary phosphino)-1-amines and Their Cp*RuCl Complexes

  摘要：

  A variety of protic 2-(tertiary phosphino)-1-amines (R2PCH2CHR'NHR '', P-NH) have been prepared from 2-ox-azolidinones and secondary phosphines using a newly developed acid-promoted decarboxylative C-P bond formation reaction. Treatment of the resulting chiral P-NH compounds with Cp*RuCl(isoprene) in CH2Cl2 smoothly furnished chiral Cp*RuCl(P-NH) complexes with a typical three-legged piano-stool structure, which prove to be excellent catalyst precursors for asymmetric reactions, including the isomerization of allylic alcohols and hydrogenation of imides.

  DOI：

  10.1021/om801042b