| 735268-84-5

• CAS: 735268-84-5
• 化学式: Cl₅IrNO
• 分子量: 399.491
• InChiKey: DOZRJWFSFANALU-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 盐酸 为溶剂， 生成 aquapentachloroiridate(IV)(1-) 、 氧化亚氮 、 hexachloroiridate(IV)
  参考文献：
  名称：

  Nikol'skii, A. B.; Popov, A. M., Doklady Physical Chemistry, 1980, vol. 250, p. 105 - 108

  摘要：

  DOI：
• 作为产物：
  描述：

  potassium pentachloronitrosyl iridate(III) 在 H₂O₂ 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  NO+, NO, NO−! Nitrosyl siblings from [IrCl5(NO)]−

  摘要：

  Pentachloronitrosyliridate(III) ([IrCl5(NO)] ), the most electrophilic NO+ known to date, can be reduced chemically and/or electrochemically by one or two electrons to produce the NO center dot and HNO/NO forms. The nitroxyl complex can be formed either by hydride attack to the NO+ in organic solvent, or by decomposition of iridium-coordinated nitrosothiols in aqueous solutions, while NO center dot is produced electrochemically or by reduction of [IrCl5(NO)] with H2O2. Both NO center dot and HNO/NO complexes are stable under certain conditions but tend to labilize the trans chloride and even the cis ones after long periods of time. As expected, the NO+ is practically linear, although the IrNO moiety is affected by the counterions due to dramatic changes in the solid state arrangement. The other two nitrosyl redox states comprise bent structures. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.063