| 155830-12-9

• CAS: 155830-12-9
• 化学式: C₃₂H₄₄Cl₄P₄Zr₂
• 分子量: 876.856
• InChiKey: VXPSGESEXGJWQL-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  氯化锆(IV) 、 二甲基苯基磷 在 Na#Hg 作用下， 以 甲苯 为溶剂， 以26.6%的产率得到
  参考文献：
  名称：

  Synthesis and structure of Zr2Cl4(η6-C6H5PMe2)2(PMe2Ph)2, an arene complex of zirconium(II)

  摘要：

  The title compound consists of two identical subunits, (PMe2Ph)Cl2Zr(eta6-C6H5PMe2), connected by the coordination of the phosphorus atom of each (eta6-C6H5PMe2) moiety to the zirconium atom of the other. There are two crystallographically distinct molecules, each on a 1BAR position, in the unit cell. In each a pyramidal trans-ZrP2Cl2 unit has an eta6-arene ring opposite and approximately parallel to the mean plane of the P2Cl2 set of atoms. The crystals are isotypic to those of the previously reported Hf2Br4(eta6-C6H5PMe2)2(PMe2Ph)2. They are triclinic, P1BAR with a=9.172(2), b=13.710(2), c=15.458(1) angstrom, alpha=101.47(1), beta=91.74(1), gamma=98.21(1)-degrees, V=1882.1(4) angstrom3, Z=2. The Zr to carbon distances are in the range 2.29-2.52 angstrom, the mean Zr-Cl distance is 2.506[12] angstrom and the Zr-P distances are in the range 2.759(2)-2.771(2) angstrom.

  DOI：

  10.1016/0020-1693(93)03762-y