[(Mn(II))3(1,4,7,10-tetraazacyclotetradecane-2,3-dione)2Cl6] | 401495-25-8

• 英文名称: [(Mn(II))3(1,4,7,10-tetraazacyclotetradecane-2,3-dione)2Cl6]
• CAS: 401495-25-8
• 化学式: C₁₆H₃₂Cl₆Mn₃N₈O₄
• 分子量: 778.013
• InChiKey: NHJQTHAYPOVQQK-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  manganese(ll) chloride 、 1,4,7,10-tetraazacyclotetradecane-2,3-dione 以 甲醇 、 乙腈 为溶剂， 以35%的产率得到[(Mn(II))3(1,4,7,10-tetraazacyclotetradecane-2,3-dione)2Cl6]
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF TRINUCLEAR MACROCYCLIC TRANSITION METAL COMPLEXES

  摘要：

  Trinuclear macrocyclic metal complexes having oxamide bridges have been synthesized by the interaction of the macrocycle 1,4,7,10-tetraazacyclotetradecane-2,3-dione with Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) chlorides and were characterized by elemental analyses, EPR, electronic, IR, H-1 NMR spectra, conductivity and magnetic susceptibility measurements. The conductivity measurements suggest that the complexes of the divalent metal ions are nonionic while those of the trivalent metal ions appear to be 1:3 electrolytes. On the basis of electronic spectra and magnetic moment values an octahedral geometry is proposed for all of the prepared complexes.

  DOI：

  10.1081/sim-100107706