[Ru(C5H5)(OC(O-t-Bu)O)(η3-phenylallyl)]PF6 | 874884-01-2

• 英文名称: [Ru(C5H5)(OC(O-t-Bu)O)(η3-phenylallyl)]PF6
• CAS: 874884-01-2
• 化学式: C₁₉H₂₃O₃Ru*F₆P
• 分子量: 545.424
• InChiKey: FJZCXLLSFJYONJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate 、 tert-butyl (1-phenylallyl) carbonate 以 丙酮 为溶剂， 以91%的产率得到[Ru(C5H5)(OC(O-t-Bu)O)(η3-phenylallyl)]PF6
  参考文献：
  名称：

  Synthesis, X-ray Studies, and Catalytic Allylic Amination Reactions with Ruthenium(IV) Allyl Carbonate Complexes

  摘要：

  Results from selected ruthenium-catalyzed allylic amination reactions, using a carbonate Ru-Cp* (or Cp) allyl cationic precursor, are reported. With a phenyl-substituted allyl substrate as the starting material, the rates of the amination reactions, as well as the regioselectivity, are shown to depend on the structure of the allyl substrate, the amine nucleophile, and the solvent. Two new Ru-allyl carbonate complexes are reported, as well as the solid-state structure for the new carbonate salt [Ru(Cp)(O2C{OBu'})(eta(3)-PhCHCHCH2)](PF6). A number of aniline- and substrate-related Cp* and Cp eta(6)-arene complexes of Ru(II) are described.

  DOI：

  10.1021/om050749o