Fe2Mg2(μ3-Br)2(μ-Br)4Br2(THF)6 | 940296-29-7

• 英文名称: Fe2Mg2(μ3-Br)2(μ-Br)4Br2(THF)6
• 英文别名: Fe2Mg2(μ3-Br)2(μ-Br)4Br2(tetrahydrofuran)6
• CAS: 940296-29-7
• 化学式: C₂₄H₄₈Br₈Fe₂Mg₂O₆
• 分子量: 1232.18
• InChiKey: DTLJBXRMUIPPKS-UHFFFAOYSA-F

反应信息

• 作为反应物：
  描述：

  Fe2Mg2(μ3-Br)2(μ-Br)4Br2(THF)6 以 四氢呋喃 为溶剂， 生成 (THF)4Mg(μ-Br)2FeBr2
  参考文献：
  名称：

  Reverse Photochromic Behavior of an Iron−Magnesium Complex

  摘要：

  We have obtained a novel heterobimetallic iron-magnesium complex, (THF)(4)Mg(mu-Br)(2)FeBr2 (THF = tetrahydrofuran), which showed reverse photochromism in THF. The response exhibited in this system is associated with d-orbital splitting of the Fe atom and a change in the molecular aggregation state (dimerization).

  DOI：

  10.1021/ic0616986
• 作为产物：
  描述：

  (THF)4Mg(μ-Br)2FeBr2 以 四氢呋喃 为溶剂， 生成 Fe2Mg2(μ3-Br)2(μ-Br)4Br2(THF)6
  参考文献：
  名称：

  Reverse Photochromic Behavior of an Iron−Magnesium Complex

  摘要：

  We have obtained a novel heterobimetallic iron-magnesium complex, (THF)(4)Mg(mu-Br)(2)FeBr2 (THF = tetrahydrofuran), which showed reverse photochromism in THF. The response exhibited in this system is associated with d-orbital splitting of the Fe atom and a change in the molecular aggregation state (dimerization).

  DOI：

  10.1021/ic0616986