[Cu(tris(2-aminoethyl)amine)]ReCl6 | 518013-07-5

• 英文名称: [Cu(tris(2-aminoethyl)amine)]ReCl6
• 英文别名: [Cu(tren)]ReCl6
• CAS: 518013-07-5
• 化学式: C₆H₁₈CuN₄*Cl₆Re
• 分子量: 608.707
• InChiKey: BWDKHFPFULGSPT-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 tetrabutylammonium hexachlororhenate(IV) 、 三(2-氨基乙基)胺 以 甲醇 为溶剂， 以96%的产率得到[Cu(tris(2-aminoethyl)amine)]ReCl6
  参考文献：
  名称：

  Ferrimagnetic, bimetallic chain systems: [Cu(tren)]ReCl6 and [Cu(tren)]ReCl6·2CH3OH where tren=tris(2-aminoethyl)amine

  摘要：

  Reaction of copper(H) chloride with tren [tris(2-aminoethyl)amine] and tetrabutylammonium hexachlororhenate [BU4N](2)ReCl6 produced a new kind of binuclear compounds: [Cu(tren)]ReCl6 (1) and [Cu(tren)]ReCl(6)(.)2CH(3)OH (2) in which [ReCl6](2-) anions and [Cu(tren)](2+) cations are held united by electrostatic forces. The magnetic behaviour of 1 and 2 has been investigated over the temperature range 1.7-300 K. Compound 1 behaves as a ferrimagnetic (CuReIV)-Re-II bimetallic, one-dimensional chain with intrachain antiferromagnetic coupling. Compound 2 shows weak antiferromagnetic interactions within Cu-II-Re-IV units. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(02)00481-7