aqua(citrate)dysprosium(III) | 1026019-60-2

• 英文名称: aqua(citrate)dysprosium(III)
• 英文别名: [Dy(citric acid(3-))(H2O)]n；[Dy(Hcit)(H2O)]n
• CAS: 1026019-60-2
• 化学式: C₆H₅O₇*Dy*H₂O
• 分子量: 369.617
• InChiKey: XIYVYQCYTJLWOO-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -6.08
• 重原子数：
  15.0
• 可旋转键数：
  5.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  172.12
• 氢给体数：
  1.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  氯化镝(III) 、 sodium citrate 生成 aqua(citrate)dysprosium(III)
  参考文献：
  名称：

  Babeshkina, Z. M.; Martynenko, L. I.; Grigor'ev, A. I., Zhurnal Neorganicheskoi Khimii, 1966, vol. 11, p. 685 - 690

  摘要：

  DOI：

文献信息

• Unusual Magnetic Behavior of a 2D Citrate‐Bridged Dysprosium(III) Coordination Polymer
  作者：Feng‐Yan Li、Lin Xu、Guang‐Gang Gao、Li‐Hua Fan、Bo Bi

  DOI：10.1002/ejic.200601113

  日期：2007.7

  A new lanthanide citrate coordination polymer [Dy(citrate)(H2O)]n (1) was hydrothermally synthesized and structurally characterized by elemental analyses, single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric analysis, photoluminescence spectrum, and magnetic measurements. The structure of 1 exhibits a 2D layer structure, in which the Dy2O2 dimer serves as the building block. The photoluminescence

  一种新的镧系元素柠檬酸配位聚合物 [Dy(citrate)(H2O)]n (1) 是水热合成的，并通过元素分析、单晶 X 射线衍射、红外光谱、热重分析、光致发光光谱和磁测量进行了结构表征。1 的结构表现出二维层结构，其中 Dy2O2 二聚体作为构建块。光致发光光谱在室温下呈固态呈蓝色发光。由于特殊的挫折结构，在化合物 1 中发现了异常的磁弛豫。 (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
• Syntheses, structures and magnetic properties of a series of 2D and 3D lanthanide complexes constructed by citric ligand
  作者：Rui-Sha Zhou、Jiang-Feng Song、Qing-Feng Yang、Xiao-Yu Xu、Ji-Qing Xu、Tie-Gang Wang

  DOI：10.1016/j.molstruc.2007.07.027

  日期：2008.4

  A series of lanthanide(III) complexes with citric ligand, [Ln(Hcit)(H2O)](n) (Ln = Ce (1), Pr (2), Sm (3), Dy (4) and Er (5)), have been synthesized and characterized by elemental analysis, IR, TGA and single-crystal X-ray diffraction. X-ray structural analysis reveals that complexes I and 2 are isomorphous and feature 3D networks showing five-connected distorted BN topology, while the isostructural 3-5 display 2D layer structures with two kinds of 13-membered rings. Variable-temperature magnetic susceptibility measurements for complexes I and 5 indicate there exist antiferromagnetic interactions between magnetic centers. (C) 2007 Elsevier B.V. All rights reserved.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sc: MVol.D5, 1.6.1.2, page 352 - 356
  作者：

  DOI：——

  日期：——