mer-{Mo(CO)3(PPh3)(P(Ph)2NHCH(CH3)2P(N2C3H(CH3)2))} | 150408-63-2

• 英文名称: mer-{Mo(CO)3(PPh3)(P(Ph)2NHCH(CH3)2P(N2C3H(CH3)2))}
• CAS: 150408-63-2
• 化学式: C₄₇H₄₄MoN₃O₃P₃
• 分子量: 887.746
• InChiKey: XMYQKXMUWWPXOG-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  fac-[Mo(CO)3(η(2)-Ph2PN(iPr)PPh(C3HN2Me2))(MeCN)] 在 Ph₃P 作用下， 以 苯 为溶剂， 以81%的产率得到mer-{Mo(CO)3(PPh3)(P(Ph)2NHCH(CH3)2P(N2C3H(CH3)2))}
  参考文献：
  名称：

  Organometallic chemistry of diphosphazanes

  摘要：

  The reaction of fac-[Mo(CO)3(MeCN)3] with the unsymmetrical diphosphazane Ph2PN(iPr)P(Ph)(DMP) (L) gives the complex fac-[Mo(CO)3(MeCN)(L)] (2) in almost quantitative yield. The structure of the complex has been determined by an X-ray diffraction study. The compound reacts with PR3 (where R = Ph, OPh) to give fac-[Mo(CO)3(PR3)(L)] (3a, 4a), which undergoes an intramolecular isomerization to afford mer-[Mo(CO)3(PR3)(L)] (3b, 4b). Synthesis of cis-[Mo(CO)4(L)] (1) and fac-[MO(CO)3L] (2a) and their spectroscopic data are also reported.

  DOI：

  10.1016/0022-328x(93)83236-o