oxotrichlorobis(cyclohexyl isocyanide)rhenium | 108695-93-8

• 英文名称: oxotrichlorobis(cyclohexyl isocyanide)rhenium
• CAS: 108695-93-8
• 化学式: C₁₄H₂₂Cl₃N₂ORe
• 分子量: 526.907
• InChiKey: LFHKBNZUMUOHRS-UHFFFAOYSA-K

反应信息

• 作为反应物：
  描述：

  oxotrichlorobis(cyclohexyl isocyanide)rhenium 、 二甲基苯基磷 以 苯 为溶剂， 生成 trichlorobis(cyclohexyl isocyanide)bis(dimethylphenylphosphine)rhenium(III)
  参考文献：
  名称：

  [ReCl3(C8H11P)2(C7H11N)2].C6H4Cl2

  摘要：

  Trichlorobis(cyclohexyl isocyanide)bis(dimethyl-phenylphosphine)rhenium(III) has been synthesized from [ReOCl3(CNCy)2] (Cy = cyclohexyl) by the removal of oxygen with excess dimethylphenylphosphine. The structure of its 1,2-dichlorobenzene adduct, determined by single-crystal X-ray methods, has a monocapped octahedral arrangement (idealized C(s) symmetry) of the seven ligands about the Re atom; the three Cl atoms adopt a fac geometry, opposite the face capped by one isocyanide ligand.

  DOI：

  10.1107/s0108270194007420
• 作为产物：
  描述：

  异氰环已烷 、 mer-[ReOCl3(SMe2)(OPPh3)] 以 四氢呋喃 为溶剂， 以58%的产率得到oxotrichlorobis(cyclohexyl isocyanide)rhenium
  参考文献：
  名称：

  Bryan, Jeffrey C.; Stenkamp, Ronald E.; Tulip, Inorganic Chemistry, 1987, vol. 26, # 14, p. 2283 - 2288

  摘要：

  DOI：