[(Me2Pt(4,4'-di-tert-butyl-2,2'-bipyridine)(p-CH2C6H4CH2COOH))2(μ-Br)]PF6 | 878475-48-0

• 英文名称: [(Me2Pt(4,4'-di-tert-butyl-2,2'-bipyridine)(p-CH2C6H4CH2COOH))2(μ-Br)]PF6
• 英文别名: [(Me2Pt(bu2bipy)(p-CH2C6H4CH2COOH))2(μ-Br)]PF6
• CAS: 878475-48-0
• 化学式: C₅₈H₇₈BrN₄O₄Pt₂*F₆P
• 分子量: 1510.31
• InChiKey: HWEZPEFXURXDGQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸银 、 (4,4'-di-tert-butyl-2,2'-bipyridine)dimethylplatinum(II) 、 4-(溴甲基)苯乙酸 以 丙酮 为溶剂， 以87%的产率得到[(Me2Pt(4,4'-di-tert-butyl-2,2'-bipyridine)(p-CH2C6H4CH2COOH))2(μ-Br)]PF6
  参考文献：
  名称：

  Self-assembly of organometallic polymers through hydrogen bonding: A diplatinum(IV) complex with a single bridging halide ligand

  摘要：

  The reaction of [PtMe2(bu(2)bipy)], bu(2)bipy = 4,4'-di-t-butyl-2,2'-bipyridine (1) with RCH2Br occurs by trans oxidative addition to give the platinum(IV) complexes [PtBrMe2(CH2R)(bu(2)bipy)], R = C6H4CO2H (2); R = C6H4CH2CO2H (3) and these reacted with half an equivalent of Ag[PF6] to give the unusual diplatinum(IV) complexes [{PtMe2(CH2R)(bu(2)bipy)}(2)(mu-Br)][PF6], R = C6H4CO2H (4); R = C6H4CH2CO2H (5). These diplatinum(IV) complexes, each of which contains a hydrogen bonding carboxylic acid group, are connected only by an unsupported bridging bromide ligand. In the solid state, complex 4 forms a self-assembled zig-zag polymer through intermolecular hydrogen bonding between pairs of carboxylic acid groups. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.08.020