tetra-n-butylammonium μ-bromobis(μ-p-chlorobenzenethiolato)bis(tricarbonylmolybdenum)(Mo-Mo) | 220148-60-7

• 英文名称: tetra-n-butylammonium μ-bromobis(μ-p-chlorobenzenethiolato)bis(tricarbonylmolybdenum)(Mo-Mo)
• CAS: 220148-60-7
• 化学式: C₁₆H₃₆N*C₁₈H₈BrCl₂Mo₂O₆S₂
• 分子量: 969.548
• InChiKey: DMOIJAGUYMMTBP-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  Mo2(μ-SC6H4-Cl-p)2(CO)8 、 四丁基溴化铵 以 丙酮 为溶剂， 生成 tetra-n-butylammonium μ-bromobis(μ-p-chlorobenzenethiolato)bis(tricarbonylmolybdenum)(Mo-Mo)
  参考文献：
  名称：

  A Hetero-Tribridged Dinuclear Molybdenum Compound [Bu₄N][Mo₂(CO)₆(p-Cl-C₆H₄S)₂Br]

  摘要：

  The title compound, tetra-n-butylammonium mu-bromo-bis(mu-p-chlorobenzenethiolato)bis(tricarbonylmolybdenum) (Mo-Mo), (C16H36N)[Mo2Br(C6H4ClS)(2)(CO)(6)], contains a Bu4N+ cation and an [Mo-2(CO)(6)(p-ClC6H4S)(2)Br](-) anion, The structure of the anion can be viewed as a cofacial bi-octahedral dimer, in which two fac-Mo(CO)(3) fragments are bridged by two p-ClC6H4S- groups and one Br- ligand. The mean Mo-Br distance is 2.765 (2) Angstrom and the Mo-Br-Mo angle is 62.68 (4)degrees.

  DOI：

  10.1107/s010827019800763x