| 154160-71-1

• CAS: 154160-71-1
• 化学式: C₆H₂CuIS
• 分子量: 296.598
• InChiKey: AQTVNFHKKRXXKA-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  copper(ll) sulfate pentahydrate 、 2-iodo-3-ethynylthiophene 在 NH₂OH*HCl 作用下， 以 乙醇 、 氨 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  三硫代环三炔（TTC）及其四钴配合物的合成与表征。含有噻吩环的脱氢环戊烯的第一个例子

  摘要：

  The planar trithienocyclotriyne (TTC) has been synthesized and structurally characterized by X-ray crystallography. TTC crystallizes in the monoclinic space group C2/c with a = 18.481-(4) angstrom, b = 10.836(2) angstrom, c = 7.490(1) angstrom, beta = 112.25(3)degrees, V = 1388.3(4) angstrom3, and Z = 4. TTC has a larger cavity size than tribenzocyclotriyne (TBC). This significantly alters the way TTC binds to transition metals in comparison to TBC. Reaction of TTC with Co2(CO)8 has produced a tetracobalt complex in which only two of the three alkynes of TTC bind to hexacarbonyl dicobalt moieties. This complex crystallizes in the triclinic space group P1BAR with a = 10.421(2) angstrom, b = 12.322(2) angstrom, c = 16.110(3) angstrom, alpha = 89.42(3)degrees, beta = 71.24(3)degrees, gamma = 66.07(3)degrees, V = 1773.1(6) angstrom3, and Z = 2.

  DOI：

  10.1021/om00014a017