| 206565-86-8

• CAS: 206565-86-8
• 化学式: C₂₂H₃₄Cl₂PZr*I
• 分子量: 618.52
• InChiKey: HBKVNSJGOKEDEJ-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  、 氯化锆(IV) 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Phosphonium-Bridged Alkali and Alkaline-Earth Metallocene Complexes¹

  摘要：

  Chiral metallocene complexes with a dialkylphosphonium bridge and different main-group metal (Li, K, Ba) centers have been synthesized from phosphonium-bridged bis(cyclopentadienyl) ligands in their mono-and diprotonated forms. NMR studies in solution and crystal structures of the kalocene Me2P(B-Me-4-tBu-C5H2)(2)K and of the barocene Me2P(2-Me-4-tBuC(5)H(2))(2)Ba(THF)(3)+BPh4- show that these metallocenes are obtained in form of their racemic diastereomers.

  DOI：

  10.1021/om971122b