(11-amino-4-methyl-5,8-diazaundeca-2,4-dien-2-olato-κ4N(5,8,11),O)-dinitrocobalt(III) | 325828-07-7

• 英文名称: (11-amino-4-methyl-5,8-diazaundeca-2,4-dien-2-olato-κ4N(5,8,11),O)-dinitrocobalt(III)
• CAS: 325828-07-7
• 化学式: C₁₀H₂₀CoN₅O₅
• 分子量: 349.293
• InChiKey: YIZJXRMILABDTL-HUDQUHEVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cobalt(III) acetylacetonate 、 N-(2-乙氨基)-1,3-丙二胺 、 sodium nitrite 以 乙腈 为溶剂， 生成 (11-amino-4-methyl-5,8-diazaundeca-2,4-dien-2-olato-κ4N(5,8,11),O)-dinitrocobalt(III)
  参考文献：
  名称：

  Conformational isomers of neutraltrans-dinitrocobalt(III) complexes

  摘要：

  The reaction of Co(acac)(3) with N-(2-aminoethyl)-1,3-propane-diamine in the presence of NaNO2 results in the preparation of an unexpected dinitrocobalt(III) compound, (11-amino-4-methyl-5,8-diazaundeca-2,4-dien-2-olato-kappa N-4(5,8,11),O)-dinitrocobalt(III), [Co(C10H20N3O)(NO2)(2)], containing the tetradentate anion of 11-amino-4-methyl-5,8-diazaundeca-2,4-dien-2-ol. Two isomers of the compound were obtained by recrystallization of the crude product. In one isomer, the two trans nitro groups are staggered, and in the other they are eclipsed.

  DOI：

  10.1107/s0108270100014463