肼-D4 | 13762-95-3

• 中文名称: 肼-D4
• 英文名称: deuterated hydrazine hydrate
• 英文别名: hydrazine-d₄；deuterated hydrazine；[(2)H4]hydrazine；hydrazine-d4；hydrazine；N2D4；1,1,2,2-tetradeuteriohydrazine
• CAS: 13762-95-3
• 化学式: H₄N₂
• 分子量: 36.0134
• InChiKey: OAKJQQAXSVQMHS-JBISRTOLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.5
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  肼-D4 以 neat (no solvent) 为溶剂， 生成 氨-d3
  参考文献：
  名称：

  Cluster size effects on hydrazine decomposition on Irn/Al2O3/NiAl(110)

  摘要：

  A series of planar model catalysts were prepared by deposition of size-selected lr(n)(+) on Al2O3/NiAl(110), and hydrazine decomposition chemistry was used to probe their size-dependent chemical properties. Small Ir-n (n <= 15) on Al2O3/NiAl(110) are able to induce hydrazine decomposition at temperatures well below room temperature, with significant activity first appearing at Ir-7. Both activity and product branching are strongly dependent on deposited cluster size, with these small clusters supporting only the simplest decomposition mechanism: dehydrogenation and N-2 desorption at low temperatures, followed by H-2 recombinative desorption at temperatures above 300 K. For Ir-15, we begin to see ammonia production, signaling the onset of a transition to clusters able to support more complex chemistry. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.susc.2005.10.054
• 作为产物：
  描述：

  乙酸-D3 、 potassium diazodicarboxylate 以 重水 为溶剂， 生成 肼-D4
  参考文献：
  名称：

  Tang; Stanbury, Inorganic Chemistry, 1994, vol. 33, # 7, p. 1388 - 1391

  摘要：

  DOI：
• 作为试剂：
  描述：

  溴化氰 在 叠氮化钾 、 肼-D4 作用下， 以 乙腈 、 水 为溶剂， 反应 9.3h， 以84.4%的产率得到deuterated 1,5-diaminotetrazole
  参考文献：
  名称：

  一种全氘代1,5-二氨基四唑的制备方法

  摘要：

  本发明公开的一种全氘代1,5‑二氨基四唑的制备方法，属于氘代含能材料的合成技术。本发明以相对安全的叠氮化钠(钾)作为原料，没有使用感度很高的叠氮化氰作为原料，操作过程安全可控，安全性高，操作流程短。本发明实现对全氘代1,5‑二氨基四唑的制备，所得产品纯度均在99.4％以上，得率相对较高，且无明显副产物生成。本发明与普通1,5‑二氨基四唑相比，全氘代1,5‑二氨基四唑的晶体密度增加4.1％，爆速由5765m/s提升至5945m/s左右，与此同时全氘代1,5‑二氨基四唑的起始分解温度提高，热稳定性增加，增加全氘代1,5‑二氨基四唑的应用范围。本发明能够为工业上生产全氘代1,5‑二氨基四唑提供参考。

  公开号：

  CN111718307A

文献信息

• Reactions of complexes of ruthenium and osmium halides with ammonia, amines, and hydrazine
  作者：J. Chatt、G. J. Leigh、Rosemary J. Paske

  DOI：10.1039/j19690000854

  日期：——

  = Cl or Br, and PR3= tertiary phosphine) in ethanol at 20° to form M(II) complexes, mer-[MX2am(PR3)3], and acetaldehyde. Secondary and tertiary amines with [MX3(PMe2Ph)3] also cause reduction, but the product is an alcohol complex [MX2(C2H5OH)(PMe2Ph)3]. The reduction may occur through a hydride complex intermediate because some hydrogen is produced in all the above reactions. The alcohol complexes

  氨和伯胺（am）在乙醇中与[MX 3（PR 3）3 ]（M = Ru或Os，X = Cl或Br，PR 3 =叔膦）在20°下反应形成M（II）配合物，mer- [MX 2 am（PR 3）3 ]和乙醛。带有[MX 3（PMe 2 Ph）3 ]的仲胺和叔胺也会引起还原，但产物是醇络合物[MX 2（C 2 H 5 OH）（PMe 2 Ph）3]。还原可通过氢化物络合物中间体发生，因为在所有上述反应中都会产生一些氢。形成醇配合物可能是出于空间原因，因为空间位阻最小的仲胺哌啶形成了哌啶配合物。
• Planar three-coordinate iron sulfide in a synthetic [4Fe-3S] cluster with biomimetic reactivity
  作者：Daniel E. DeRosha、Vijay G. Chilkuri、Casey Van Stappen、Eckhard Bill、Brandon Q. Mercado、Serena DeBeer、Frank Neese、Patrick L. Holland

  DOI：10.1038/s41557-019-0341-7

  日期：2019.11

  four-coordinate iron sites of typical iron-sulfur clusters rarely react with substrates, implicating three-coordinate iron. This idea is untested because fully sulfide-coordinated three-coordinate iron is unprecedented. Here we report a new type of [4Fe-3S] cluster that features an iron centre with three bonds to sulfides, and characterize examples of the cluster in three oxidation levels using crystallography

  铁-硫簇正在作为减少小分子底物还原的反应位点而出现。但是，典型的铁硫簇的四坐标铁位点很少与底物反应，这意味着三坐标铁。这个想法未经检验，因为完全硫化物配位的三配位铁是史无前例的。在这里，我们报告了一种新型的[4Fe-3S]团簇，该团簇具有一个与硫化物具有三个键的铁中心，并使用晶体学，光谱学和从头算计算来表征该团簇在三个氧化水平上的示例。尽管高旋转电子构型是其他铁硫簇的特征，但由于平面几何形状和短的Fe-S键，这些簇中的三坐标铁中心具有令人惊讶的低旋转电子构型。在仿生反应性的演示中，[4Fe-3S]团簇可还原肼，这是固氮酶的天然底物。产物是结合到铁硫簇上的NH2的第一个例子。我们的结果表明，由硫化物供体支撑的三配位铁是在铁-硫团簇（如固氮酶的FeMoco）中发生反应的合理前体。
• Borane B−C Bond Cleavage by a Low-Coordinate Iron Hydride Complex and N−N Bond Cleavage by the Hydridoborate Product
  作者：Ying Yu、William W. Brennessel、Patrick L. Holland

  DOI：10.1021/om7003805

  日期：2007.6.1

  The iron(II) hydride dimers [(LFe)-Fe-R(mu-H)(2)FeLR] (L-Me = 2,4-bis(2,6-diisopropylphenylimino)pent-3-yl; L-tBu = 2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl) abstract hydrocarbyl groups from BR'(3) (R' = Et, Ph) to give (LFeR)-Fe-R' and (LFe)-Fe-R(mu-H)(2)BR'(2). Mechanistic studies with R = R' = Me are consistent with a process in which the hyride dimer opens one Fe-H bond, and subsequent B-H bond formation is concerted with dissociation of an Fe-H unit. Cleavage of boron-carbon bonds is likely to proceed at least in part from transient quaternary borate anions formed through disproportionation of HBEt3-. In a separate bond-breaking reaction, (LFe)-Fe-Me(mu-H)(2)BEt2 reacts with N2H4 to form a 1:1 adduct, which has been crystallographically characterized. Upon heating, it ejects H-2 from the bridging hydrides and cleaves the N-N bond to form the diaminoborate complex (LFe)-Fe-Me(mu-NH2)(2)BEt2. These novel bond-breaking reactions are facilitated by the low coordination number at the iron(II) center.
• Sharov, V. A.; Bezdenezhnykh, G. V., Russian Journal of Inorganic Chemistry, 1994, vol. 39, p. 1947 - 1949
  作者：Sharov, V. A.、Bezdenezhnykh, G. V.

  DOI：——

  日期：——
• Unusual Thiolate-Bridged Diiron Clusters Bearing the <i>cis</i>-HN═NH Ligand and Their Reactivities with Terminal Alkynes
  作者：Yanhui Chen、Litao Liu、Ying Peng、Pingping Chen、Yi Luo、Jingping Qu

  DOI：10.1021/ja105948r

  日期：2011.2.9

  A series of well-defined thiolate-bridged diiron clusters bearing the cis-HN = NH ligand, [Cp+Fe(mu-SEt)(2)-(mu-eta(1):eta(1)-HN = NH)FeCp+][PF6] (Cp+ = eta(5)-C5Me4H or eta(5)-C5Me5), are successfully prepared in high yields and fully characterized by spectroscopy and X-ray crystallography. Under moderate conditions, these new Fe/S clusters exhibit high activity, not only for the catalytic cleavage of the N-N bond of hydrazines but also for the activation and coupling of terminal alkynes.