trans-chlorobis(diphenylglyoximato)(tri-n-butylphosphine)cobalt(III) | 190712-55-1

• 英文名称: trans-chlorobis(diphenylglyoximato)(tri-n-butylphosphine)cobalt(III)
• CAS: 190712-55-1
• 化学式: C₄₀H₄₉ClCoN₄O₄P
• 分子量: 775.273
• InChiKey: BUJQLMRKRIBCQB-AGMWPDPBSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三丁基膦 、 cobalt(II) diacetate tetrahydrate 、 二联苯乙二醛肟 、 sodium chloride 以 乙醇 、 水 为溶剂， 以70%的产率得到trans-chlorobis(diphenylglyoximato)(tri-n-butylphosphine)cobalt(III)
  参考文献：
  名称：

  trans-Chlorobis(diphenylglyoximato)(tri-n-butylphosphine)cobalt(III)

  摘要：

  The Co atom in the title cobaloxime, [CoCl(C14H11N2O2)(2)(C12H27P)], is octahedrally coordinated to the two bidentate diphenylglyoximato ligands, approximating a plane with the Cl and P atoms located above and below the plane. The diphenylglyoximato moieties are themselves bent 6.6(1) and 9.8(1)degrees from the central plane of the four N atoms by the bulk of the trin-butylphosphine ligand. The four phenyl rings of the two diphenylglyoximato groups form a propeller geometry with an average rotation from the central plane of 47 (5)degrees.

  DOI：

  10.1107/s010827019601565x