tricarbonyl[(4,6-η(3))-3-vinyl-2-oxa-1-oxo-5-hexen-1,4-diyl]iron(II) | 61916-86-7

• 英文名称: tricarbonyl[(4,6-η(3))-3-vinyl-2-oxa-1-oxo-5-hexen-1,4-diyl]iron(II)
• CAS: 61916-86-7
• 化学式: C₁₀H₈FeO₅
• 分子量: 264.018
• InChiKey: TVYYDFNIRXHQQY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  tricarbonyl[(4,6-η(3))-3-vinyl-2-oxa-1-oxo-5-hexen-1,4-diyl]iron(II) 、 trimethoxonium tetrafluoroborate 以 二氯甲烷 为溶剂， 以63%的产率得到tricarbonyl[(4,6-η(3))-3-ethylen-1-methoxy-2-oxa-5-hexen-4-yl-1-ylidene]iron(II) tetrafluoroborate
  参考文献：
  名称：

  New ferracyclic π-allyl and η3-pentadienyl complexes by carbonylative lactonization of unsaturated diols

  摘要：

  Various types of mono- and binuclear ferracyclic (eta(3)-allyl)iron complexes were prepared from unsaturated diols. Chelated tricarbonylironcarbene complexes 5 and 7 featuring a partially ligated (1,3-eta(3))-pentadienyl ligand were built up from the diene-1,2-diols 4 or 8, respectively. 2-Hexyn-4-ene-1,6-diol (12) reacted with enneacarbonyldiiron to furnish the binuclear 1-lactonyl-(1,3-pi:2-sigma)-allyldiiron complex 13 under mild conditions. Its structural details are discussed. Similar complexes 17 with five- to seven-membered lactone substituents at the allyl ligand were prepared likewise from the corresponding 2-alkyne-1,n-diols (16). (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00041-9
• 作为产物：
  描述：

  diiron nonacarbonyl 、 4,5-divinyl-[1,3,2]dioxathiolan-2-oxide 以 苯 为溶剂， 以55%的产率得到tricarbonyl[(4,6-η(3))-3-vinyl-2-oxa-1-oxo-5-hexen-1,4-diyl]iron(II)
  参考文献：
  名称：

  New ferracyclic π-allyl and η3-pentadienyl complexes by carbonylative lactonization of unsaturated diols

  摘要：

  Various types of mono- and binuclear ferracyclic (eta(3)-allyl)iron complexes were prepared from unsaturated diols. Chelated tricarbonylironcarbene complexes 5 and 7 featuring a partially ligated (1,3-eta(3))-pentadienyl ligand were built up from the diene-1,2-diols 4 or 8, respectively. 2-Hexyn-4-ene-1,6-diol (12) reacted with enneacarbonyldiiron to furnish the binuclear 1-lactonyl-(1,3-pi:2-sigma)-allyldiiron complex 13 under mild conditions. Its structural details are discussed. Similar complexes 17 with five- to seven-membered lactone substituents at the allyl ligand were prepared likewise from the corresponding 2-alkyne-1,n-diols (16). (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00041-9