CpCo(μ-C₃B₂Me₅)Rh(C₂H₄)₂ | 1609011-86-0

• 英文名称: CpCo(μ-C₃B₂Me₅)Rh(C₂H₄)₂
• CAS: 1609011-86-0
• 化学式: C₁₇H₂₈B₂CoRh
• 分子量: 415.93
• InChiKey: GGOPOHJZWCJHGL-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  chlorobis(ethylene)rhodium(I) dimer 、 [CpCo(μ-C₃B₂Me₅)]Tl 以 四氢呋喃 为溶剂， 以81%的产率得到CpCo(μ-C₃B₂Me₅)Rh(C₂H₄)₂
  参考文献：
  名称：

  Triple-decker complex CpCo(μ-C3B2Me5)Rh(C2H4)2: Synthesis, structure and bonding

  摘要：

  The reaction of the thallium derivative [CpCo(mu-C3B2Me5)]Tl with [Rh(C2H4)(2)Cl](2) affords the mu-diborolyl bis(ethylene) triple-decker complex CpCo(mu-C3B2Me5) Rh(C2H4)(2) (4). Structure of 4 was determined by X-ray diffraction. According to DFT calculations, the ethylene dissociation energies for the triple-decker complexes CpCo(mu-C3B2R5) Rh(C2H4)(2) (R = H, Me) are ca. 6 kcal mol(-1) lower than for cyclopentadienyl analogs (C5R5) Rh(C2H4)(2). Energy decomposition analysis revealed that the bonding of anions [CpCo (C3B2R5)] - with [Rh(C2H4)(2)](+) is also weaker than that of [C5R5] -; the attractive interactions in both cases are 60-63% electrostatic and 37-40% covalent. The electrostatic potentials at the Rh nuclei suggest that the donor ability of the anions increases in the following order: Cp < [CpCo(C3B2H5)] <= [CpCo(C3B2Me5)] < Cp*. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2014.02.033