[(2,2'-bipyridine)tetrabromorhenium] | 17099-95-5

• 英文名称: [(2,2'-bipyridine)tetrabromorhenium]
• CAS: 17099-95-5
• 化学式: C₁₀H₈Br₄N₂Re
• 分子量: 662.01
• InChiKey: FOEXJTLVGDGWRP-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三溴甲烷 、 mer-[(2,2'-bipyridine)tribromooxorhenium] 在 triphenylphosphine 作用下， 以 三溴甲烷 为溶剂， 以60%的产率得到[(2,2'-bipyridine)tetrabromorhenium]
  参考文献：
  名称：

  The reactivity of mer-[ReOBr3(bipy)] towards gaseous nitric oxide. The crystal, molecular and electronic structure of mer-[ReOBr3(bipy)] and [ReBr4(bipy)]

  摘要：

  The reactivity of mer-[ReOBr3(bipy)] (1) (bipy = bipyridine) towards gaseous nitric oxide has been investigated. The reaction of 1 with NO in bromoform has afforded only starting material, but in the presence of an excess of triphenylphosphine, the [ReBr3(NO)(bipy)] (3) has been obtained. Refluxing of 1 and PPh3 in CHBr3 has led to the isolation of [ReBr4(bipy)] (2). The complexes 1, 2 and 3 were characterised by IR, UV-Vis and magnetical measurements. Crystal and molecular structures of 1 and 2 have been determined. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00350-4