Mn2(μ-Br)(μ-PH2)(CO)8 | 66683-31-6

• 英文名称: Mn2(μ-Br)(μ-PH2)(CO)8
• CAS: 66683-31-6
• 化学式: C₈H₂BrMn₂O₈P
• 分子量: 446.853
• InChiKey: YRNGHUCYQWZLOJ-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  五羰基溴化锰(I) 、 Mn2(μ-Br)(μ-PH2)(CO)8 以 四氢呋喃 为溶剂， 生成 μ-bromo-1:2κ(2)Br-tridecacarbonyl-1κ(4)C,2κ(4)C,3κ(5)C-μ3-phosphanido-1:2:3κ(3)P-trimanganese
  参考文献：
  名称：

  μ-Bromo-μ-cyclohexylphosphido-bis(tetracarbonylmanganese) and μ-Bromo-μ-(pentacarbonylmanganese)phosphido-bis(tetracarbonylmanganese)

  摘要：

  The central molecular fragment of the first title complex, [Mn2Br(C6H12P)(CO)(8)], is a four-membered non-planar Mn2BrP ring with a cyclohexyl ring and a H atom attached to the bridging P atom. In the related second title complex, [Mn3Br(PH)(CO)(13)], the cyclohexyl ligand is substituted by an Mn(CO)(5) group which displays an unusual ecliptic arrangement with the axial carbonyl ligands of the ring Mn atoms.

  DOI：

  10.1107/s0108270197000735