tetracarbonyl-1κ(2)C,2κ(2)C-μ-diphenylphosphido-P:P-μ-iodo-bis(triphenylphosphine)-1κP,2κP-diosmium(Os-Os) benzene solvate | 188545-33-7

• 英文名称: tetracarbonyl-1κ(2)C,2κ(2)C-μ-diphenylphosphido-P:P-μ-iodo-bis(triphenylphosphine)-1κP,2κP-diosmium(Os-Os) benzene solvate
• CAS: 188545-33-7
• 化学式: C₆H₆*C₅₂H₄₀IO₄Os₂P₃
• 分子量: 1407.23
• InChiKey: GFFOBILTRPGIOD-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  Os2(μ-PPh2)(μ-I)(CO)6 以 正庚烷 为溶剂， 生成 tetracarbonyl-1κ(2)C,2κ(2)C-μ-diphenylphosphido-P:P-μ-iodo-bis(triphenylphosphine)-1κP,2κP-diosmium(Os-Os) benzene solvate
  参考文献：
  名称：

  Tetracarbonyl-1κ²C,2κ²C-μ-diphenylphosphido-P:P-μ-iodo-bis(triphenylphosphine)-1κP,2κP-diosmium(Os—Os) Benzene Solvate

  摘要：

  In the title compound, [Os2I(C12H10P)(C18H15P)(2)-(CO)(4)].C6H6, the Os-Os bond distance is unusually short [2.781 (1) Angstrom]. The two Os atoms are symmetrically bridged by both an iodo and a phosphido ligand. Two carbonyl groups and a triphenylphospine moiety complete the Os-atom coordination spheres. There are only two other reported structures with an iodo ligand bridging two Os atoms [Sutton, Nivin & Moss (1983).

  DOI：

  10.1107/s0108270196013911