((2,6-bis(1-methylbenzimidazole-2-yl)pyridine)(Cl)Ru)2Cl2 | 1210397-31-1

• 英文名称: ((2,6-bis(1-methylbenzimidazole-2-yl)pyridine)(Cl)Ru)2Cl2
• 英文别名: (Ru(2,6-bis(1-methyl-1H-benzo[d]imidazol-2-yl)pyridine)(Cl))₂Cl₂；[((2,6-bis(1-methylbenzimidazol-2-yl)pyridine)(Cl)Ru)2Cl2]
• CAS: 1210397-31-1；1268524-46-4
• 化学式: C₄₂H₃₄Cl₄N₁₀Ru₂
• 分子量: 1022.75
• InChiKey: HDDXCQILNFCECL-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ((2,6-bis(1-methylbenzimidazole-2-yl)pyridine)(Cl)Ru)2Cl2 以 甲醇 、 乙醇 、 水 为溶剂， 生成 [Ru(2,6-bis(1-methylbenzimidazol-2-yl)pyridine)(2,2′-bipyridine)(triflate)](triflate)
  参考文献：
  名称：

  单中心钌络合物催化剂氧化水的机理

  摘要：

  [Ru(tpy)(bpm)(OH(2))](2+) (tpy = 2,2':6',2''-三联吡啶；bpm = 2)催化Ce(IV)水氧化的机理,2'-联嘧啶) 和相关的单中心催化剂已通过混合和停流实验与分光光度监测的组合确定。该机制的特点是通过水攻击对 Ru(V)=O(3+) 和三种过氧化物中间体进行 O---O 耦合，这些中间体已通过光谱学和 DFT 计算的组合进行表征。

  DOI：

  10.1021/ja904906v
• 作为产物：
  描述：

  N-甲基-1,2-苯二胺 在 ruthenium(III) chloride trihydrate 、 磷酸 、 三乙胺 作用下， 以 乙醇 为溶剂， 反应 9.0h， 生成 ((2,6-bis(1-methylbenzimidazole-2-yl)pyridine)(Cl)Ru)2Cl2
  参考文献：
  名称：

  Ruthenium or osmium complexes and their uses as catalysts for water oxidation

  摘要：

  本发明提供了钌或锇配合物及其用作催化水氧化的催化剂。发明的另一个方面提供了用于电解水分子的电极和光电化学电池。

  公开号：

  US08524903B2

文献信息

• Silatranes for binding inorganic complexes to metal oxide surfaces
  作者：Kelly L. Materna、Bradley J. Brennan、Gary W. Brudvig

  DOI：10.1039/c5dt03463a

  日期：——

  Silatranes do not react when synthesizing inorganic complexes and form bonds to metal oxide surfaces that are stable under acidic, neutral, and basic conditions.

  硅杂环烷在合成无机配合物时不发生反应，并且与金属氧化物表面形成的键在酸性、中性和碱性条件下都很稳定。
• Self-Assembled Bilayers as an Anchoring Strategy: Catalysts, Chromophores, and Chromophore-Catalyst Assemblies
  作者：Lei Wang、Dmitry E. Polyansky、Javier J. Concepcion

  DOI：10.1021/jacs.9b01044

  日期：2019.5.22

  Anchoring strategies for immobilization of molecular catalysts, chromophores, and chromophore-catalyst assemblies on electrode surfaces play an important role in solar energy conversion devices such as dye sensitized solar cells and dye-sensitized photoelectrosynthesis cells. They are also important in interfacial studies with surface-bound molecules including electron-transfer dynamics and mechanistic studies related to small molecule activation catalysis. Significant progress has been made in this area, but many challenges remain in terms of stability, synthetic complexity, and versatility. We report here a new anchoring strategy based on self assembled bilayers. This strategy takes advantage of noncovalent interactions between long alkyl chains chemically bound to a metal-oxide electrode surface and long alkyl chains on the molecule being anchored. The new methodology is applicable to the heterogenization of both catalysts and chromophores as well as to the in situ "synthesis" of chromophore-catalyst assemblies on the electrode surface.