triazido(tripyridino)indium | 259533-33-0

• 英文名称: triazido(tripyridino)indium
• CAS: 259533-33-0
• 化学式: C₁₅H₁₅InN₁₂
• 分子量: 478.185
• InChiKey: ICWKDAMAUPUDNJ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  吡啶 、 sodium azide 、 氯化铟 以 甲苯 为溶剂， 生成 triazido(tripyridino)indium
  参考文献：
  名称：

  Organoindium azides: new precursors to indium nitride

  摘要：

  The synthesis, properties and the molecular structure in the solid state of triazido(tripyridino)indium (1), the mixed coordination polymer {(CF3SO3)In[(CH2)(3)NMe2)](2)(mu-N-3)In[(CH2)(3)NMe2)](2)}(x), (2) and the polymeric monoazide {(N-3)In[(CH2)(3)NMe2)](2)} (3) are reported. Some aspects of the precursor chemistry of 1-3 related to the synthesis of InN thin films are discussed, with special emphasis on the aspect of the accessible chemical purity of the precursors. Compound 3 al:owed the growth of crystalline InN thin films at 300-450 degrees C in the absence of ammonia using the technique of organometallic chemical vapor deposition. (C) 1997 Elsevier Science B.V.

  DOI：

  10.1016/s0022-328x(97)00333-1