tetrachloro(2,3,6,7,13,14,17,18-octamethyl-1,4,5,8,12,15,16,19-octaazacyclodocosane-1,3,5,7,12,14,16,18-octaene) dinickel(II) | 165286-99-7

• 英文名称: tetrachloro(2,3,6,7,13,14,17,18-octamethyl-1,4,5,8,12,15,16,19-octaazacyclodocosane-1,3,5,7,12,14,16,18-octaene) dinickel(II)
• CAS: 165286-99-7
• 化学式: C₂₂H₃₆Cl₄N₈Ni₂
• 分子量: 671.773
• InChiKey: ORLHPXSUUBJLGX-WSIUREPTSA-J

反应信息

• 作为产物：
  描述：

  1,3-丙二胺 、 nickel(II) chloride hexahydrate 、 3,6-dimethyl-4,5-diazaocta-3,5-diene-2,7-dione 以 甲醇 为溶剂， 以42%的产率得到tetrachloro(2,3,6,7,13,14,17,18-octamethyl-1,4,5,8,12,15,16,19-octaazacyclodocosane-1,3,5,7,12,14,16,18-octaene) dinickel(II)
  参考文献：
  名称：

  Transition metal complexes of 20–22-membered octaazamacrocycles: Synthesis and characterization

  摘要：

  A series of binuclear octaazamacrocyclic complexes [M(2)L(1)X(4)]-[M(2)L(2)X(4)] (M = Ni-II, Co-II and Zn-II;X = Cl or NO3) and [Cu(2)L(1)]X(4)-[Cu(2)L(2)]X(4) (X = Cl or NO3) have been synthesized by template condensation reaction of aliphatic primary diamines with 3,6-dimethyl-4,5-diazaocta-3,5-diene-2,7-dione in methanol. The overall geometry and stereochemistry of these complexes have been elucidated by IR, H-1 NMR, EPR and electronic spectral studies, and magnetic susceptibility and conductance values. An octahedral geometry around the metal ion is suggested for nickel, cobalt and zinc complexes, whilst a square planar geometry is proposed for copper complexes.

  DOI：

  10.1016/0277-5387(94)00395-u