[Rh(cod)(4,4'-bis(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-ylidene)]OTf | 1339900-30-9

• 英文名称: [Rh(cod)(4,4'-bis(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-ylidene)]OTf
• CAS: 1339900-30-9
• 化学式: CF₃O₃S*C₃₈H₅₂N₆Rh
• 分子量: 844.847
• InChiKey: AVGNOQNHRGPPLN-ONEVTFJLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  一氧化碳 、 [Rh(cod)(4,4'-bis(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-ylidene)]OTf 以 氯仿 为溶剂， 以60%的产率得到[Rh(CO)2(4,4'-bis(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-ylidene)]OTf
  参考文献：
  名称：

  Bis(1,2,3-triazol-5-ylidenes) (i-bitz) as Stable 1,4-Bidentate Ligands Based on Mesoionic Carbenes (MICs)

  摘要：

  Direct metalation of bis(1,2,3-triazolium) salts affords mononuclear rhodium(I) complexes, which feature a 1,4-bidentate bis(1,2,3-triazol-5-ylidene) (i-bitz) ligand. The topology of the ligand is similar to that of 2,2'-bipyridines (bpy) and their congeners, as well as bis(1,2,4-triazol-5-ylidenes) (bitz). As the former, but in contrast to the latter, the free i-bitz can be isolated, which paves the way for various applications.

  DOI：

  10.1021/om200844b
• 作为产物：
  描述：

  乙醇 、 1,1'-bis(2,6-diisopropylphenyl)-3,3'-dimethyl-1H,1'H-4,4'-bis(1,2,3-triazolium) trifluoromethanesulfonate 、 chloro(1,5-cyclooctadiene)rhodium(I) dimer 在 NaH 作用下， 以 乙醇 为溶剂， 以86%的产率得到[Rh(cod)(4,4'-bis(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-ylidene)]OTf
  参考文献：
  名称：

  Bis(1,2,3-triazol-5-ylidenes) (i-bitz) as Stable 1,4-Bidentate Ligands Based on Mesoionic Carbenes (MICs)

  摘要：

  Direct metalation of bis(1,2,3-triazolium) salts affords mononuclear rhodium(I) complexes, which feature a 1,4-bidentate bis(1,2,3-triazol-5-ylidene) (i-bitz) ligand. The topology of the ligand is similar to that of 2,2'-bipyridines (bpy) and their congeners, as well as bis(1,2,4-triazol-5-ylidenes) (bitz). As the former, but in contrast to the latter, the free i-bitz can be isolated, which paves the way for various applications.

  DOI：

  10.1021/om200844b