[η(5):η(1)-C5Me4(CH2)3O]Ti(CH2Ph)2 | 208930-98-7

• 英文名称: [η(5):η(1)-C5Me4(CH2)3O]Ti(CH2Ph)2
• CAS: 208930-98-7
• 化学式: C₂₆H₃₂OTi
• 分子量: 408.419
• InChiKey: BYGYOSWBJXDULK-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [η(5):η(1)-C5Me4(CH2)3O]Ti(CH2Ph)2 、 三(五氟苯基)硼烷 以 further solvent(s) 为溶剂， 生成 ([η(5):η(1)-C5Me4(CH2)3O]Ti(η(2)-CH2Ph))[PhCH2B(C6F5)3]
  参考文献：
  名称：

  Titanium Hydrocarbyl Complexes with a Linked Cyclopentadienyl−Alkoxide Ancillary Ligand; Participation of the Ligand in an Unusual Activation of a (Trimethylsilyl)methyl Group

  摘要：

  The titanium complexes [eta(5):eta(1)-C5Me4(CH2)(3)O]TiR2 (R = CI, Me, CH2Ph, CH2CMe3, CH2SiMe3), with a linked Cp-alkoxide ancillary ligand, have been prepared in good yield. Cationic [C5Me4(CH2)(3)O]Ti(eta(2)-CH2Ph)(+) catalyzes the polymerization of propene to atactic polypropene. B(C6F5)(3) reacts with [C5Me4(CH2)(3)O]Ti(CH2SiMe3)(2) by Me abstraction from one of the CH2SiMe3 groups accompanied by an, attack of the ligand alkoxide functionality on the Si atom of this group.

  DOI：

  10.1021/om970867e
• 作为产物：
  描述：

  (tetramethyl(methoxypropyl)cyclopentadienyl)titanium chloride 、 苯基锂 以 not given 为溶剂， 生成 [η(5):η(1)-C5Me4(CH2)3O]Ti(CH2Ph)2
  参考文献：
  名称：

  Titanium Hydrocarbyl Complexes with a Linked Cyclopentadienyl−Alkoxide Ancillary Ligand; Participation of the Ligand in an Unusual Activation of a (Trimethylsilyl)methyl Group

  摘要：

  The titanium complexes [eta(5):eta(1)-C5Me4(CH2)(3)O]TiR2 (R = CI, Me, CH2Ph, CH2CMe3, CH2SiMe3), with a linked Cp-alkoxide ancillary ligand, have been prepared in good yield. Cationic [C5Me4(CH2)(3)O]Ti(eta(2)-CH2Ph)(+) catalyzes the polymerization of propene to atactic polypropene. B(C6F5)(3) reacts with [C5Me4(CH2)(3)O]Ti(CH2SiMe3)(2) by Me abstraction from one of the CH2SiMe3 groups accompanied by an, attack of the ligand alkoxide functionality on the Si atom of this group.

  DOI：

  10.1021/om970867e