dichloro(η(5)-cyclopentadienyl)(phenylimido)vanadium(V) | 187096-74-8

• 英文名称: dichloro(η(5)-cyclopentadienyl)(phenylimido)vanadium(V)
• CAS: 187096-74-8
• 化学式: C₁₁H₁₀Cl₂NV
• 分子量: 278.055
• InChiKey: UIYYTXPLTAHNDO-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  dichloro-η(5)-cyclopentadienyl-tert-butylimido-vanadium(V) 、 苯胺 以 1,2-二氯乙烷 为溶剂， 以47%的产率得到dichloro(η(5)-cyclopentadienyl)(phenylimido)vanadium(V)
  参考文献：
  名称：

  Dichloro(η⁵-cyclopentadienyl)(phenylimido)vanadium(V)

  摘要：

  The title compound, [VCl2(C5H5)(C6H5N)], contains vanadium in a tetrahedral coordination geometry, with the cyclopentadienyl (Cp) ligand occupying one of the four sites and showing an allyl-ene distortion. The V-N-C angle is 169.1 (4)degrees. The crystal packing involves C-H ... Cl interactions, with H ... Cl distances in the range 2.87 (5)-2.89 (4) Angstrom.

  DOI：

  10.1107/s0108270196012875