[Co(η5-C5H4C(O)NHC6H5)2]Br * H2O | 163393-74-6

• 英文名称: [Co(η5-C5H4C(O)NHC6H5)2]Br * H2O
• CAS: 163393-74-6
• 化学式: Br*C₂₄H₂₀CoN₂O₂*H₂O
• 分子量: 525.347
• InChiKey: MCSLSKBEBIYNSB-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  氢溴酸 、 1,1'-bis{(N-phenyl)aminocarbonyl}cobaltocenium hexafluorophosphate 以 水 、 乙腈 为溶剂， 生成 [Co(η5-C5H4C(O)NHC6H5)2]Br * H2O
  参考文献：
  名称：

  Quantitative and structural investigations of hydrogen bonding interactions in anion binding of mono- and 1,1′-bis-substituted aryl cobaltocenium receptors

  摘要：

  New acyclic monosubstituted aryl cobaltocenium derivatives, functionalised with additional hydrogen-bonding amine groups have been prepared. Quantitative investigation of the anion-binding properties by H-1 NMR spectroscopy and electrochemical methods shows enhanced binding believed to be due to amine group participation in hydrogen bonding. Similar recognition studies on 1,1'-bissubstituted aryl cobaltocenium analogues indicate an order of magnitude selectivity for the dihydrogenphosphate anion over simple halide anions. The importance of hydrogen bonding is also illustrated by the first single-crystal structure showing the anion complex of a cobaltocenium receptor.

  DOI：

  10.1039/dt9950000403