| 692732-05-1

• CAS: 692732-05-1
• 化学式: C₂₀H₁₆Cu₂F₂N₄O₃
• 分子量: 525.461
• InChiKey: WQXFKKRDVAAXHU-FAVRNVGXSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡唑 、 copper(II) perchlorate hexahydrate 、 3-氟-2-羟基苯甲醛 、 1,3-二氨基-2-羟基丙烷 在 triethylamine 作用下， 以 甲醇 为溶剂， 以51%的产率得到
  参考文献：
  名称：

  Syntheses, structures, and magnetic properties of two new μ-alkoxo-μ-pyrazolato bridged dicopper(II) complexes

  摘要：

  The syntheses, structures, and magnetic properties of two new mu-alkoxo-mu-pyrazolato heterobridged compounds, [Cu-2(II)(L-1-F)(mu-prz)] (1) and [Cu-2(II)(L-1-2OMe) (mu-prz)](.)0.5 CH3CN (2) (prz = pyrazolato; H2L1-F = 1,3-bis(3-fluorosalicylideneamino)-2-propanol; H2L1-2OMe = 1,3-bis(4,6-dimethoxy salicylideneamino)-2-propanol) have been reported. Compound 1 crystallizes in trichnic P (1) over bar space group with a = 8.6392(10) Angstrom, b = 10.6431(9) Angstrom, c = 11.6809(13) Angstrom, alpha = 85.972(8)degrees, beta = 71.492(9)degrees, and gamma = 72.221(9)degrees, while the unit cell parameters of 2 are as follows: space group: monoclinic C2/c, a = 28.2948(5) Angstrom, b = 7.3033(2) Angstrom, c = 26.3933(5) Angstrom, and beta = 96.243(1)degrees. The variable-temperature magnetic Susceptibility measurements reveal that the metal centers in both the compounds are antiferromagnetically coupled with J = -200 cm(-1) for 1 and J = - 175 cm(-1) for 2. The magnetic behaviors have been explained on the basis of two opposing factors, complementarity and countercomplementarity of magnetic orbitals. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.11.021