bis[η5-2,5-dicyclohexyl-P-tetracarbonyliron(0)-1-phosphacyclopentadienyl]ruthenium(II) | 448901-41-5

• 英文名称: bis[η5-2,5-dicyclohexyl-P-tetracarbonyliron(0)-1-phosphacyclopentadienyl]ruthenium(II)
• CAS: 448901-41-5
• 化学式: C₄₀H₄₈Fe₂O₈P₂Ru
• 分子量: 931.528
• InChiKey: DQKFMTOXRWNQOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  diiron nonacarbonyl 、 bis[η5-2,5-dicyclohexyl-1-phosphacyclopentadienyl]ruthenium(II) 以 苯 为溶剂， 以90%的产率得到bis[η5-2,5-dicyclohexyl-P-tetracarbonyliron(0)-1-phosphacyclopentadienyl]ruthenium(II)
  参考文献：
  名称：

  Synthesis and Characterization of 1,1‘-Diphospharuthenocenes

  摘要：

  Reaction of [RuCl2(cod)](n) (cod = 1,5-cyclooctadiene) with lithium 2,5-dialkylphospholide or 1-stannyl-2,5-dialkylphosphole gives Ru(eta(5)-PC4H2-2,5-R-2)(2) (R = (-)-menthyl, 4a; or cyclohexyl, 4b). Steric bulkiness of the R groups is a crucial factor for the successful preparation of the 1,1'-diphospharuthenocenes. The structure of the complex 4b was studied by X-ray single-crystal structure determination, which clarified the distance between the nearly planar eta(5)-phospholyl ligand and the ruthenium center in the complex, being 1.811 Angstrom.

  DOI：

  10.1021/om020189i