| 228123-46-4

• CAS: 228123-46-4
• 化学式: C₁₆H₁₈B₁₀N₂S₄
• 分子量: 474.706
• InChiKey: REBOVSILZVVEPF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 四丁基氟化铵 在 NBu₄F 作用下， 以 四氢呋喃 为溶剂， 以45%的产率得到
  参考文献：
  名称：

  Synthesis of some new mono- and di-substituted o-carborane derivatives with thiolate and carbamate moieties: crystal structure of 1-(SNC5H4)-1,2-C2B10H11

  摘要：

  Some new o-carborane derivatives of stoichiometry 1,2-(SR)(2)-1,2-C2B10H10 [SR=S2NC7H4, S2CNEt2] have been synthesised by reaction of 1,2-Li-2-1,2-C2B10H10 with the corresponding disulfide derivatives RSSR (RSSR=(C7H4NS2)(2), 2,2'-dithiobis(benzothiazole); (Et,NCS,), tetraethylthiuram disulfide) in molar ratio 1:2. The reaction of 1-Li-2-(SiBuMe2)-Bu-t-1,2-C2B10H10 with RSSR (RSSR= (C5H4NS)(2), 2,2'-dithiodipyridine; (C7H4NS2)(2)) in molar ratio 1:1 has afforded the new mixed di-substituted compounds 1-SR-2-(SiBuMe2)-Bu-t-1,2-C2B10H10 (SR=SNC5H4; S2NC7H4). The reaction of 1-SNC5H4-2-(SiBuMe2)-Bu-t- 1,2-C2B10H10 with NBu4F in THF in molar ratio 1:2 has afforded the mono-substituted derivative 1-SNC5H4-1,2-C2B10H10, whereas the treatment of 1,2-(C7H4NS2)(2)-1,2-C2B10H10 with NBu4F in THF in molar ratio 1:5 has led to the partially degraded derivative NBu4[7,8-(S2NC7H4)(2)-7,8-C2B9H10]. The crystal structure of 1-SNC5H4-1,2-C2B10H11 has been determined by X-ray diffraction. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00430-6
• 作为产物：
  描述：

  1,2-dicarba-closo-dodecaborane(12) 、 二硫化二苯并噻唑 在 BuLi 作用下， 以 乙醚 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  Synthesis of some new mono- and di-substituted o-carborane derivatives with thiolate and carbamate moieties: crystal structure of 1-(SNC5H4)-1,2-C2B10H11

  摘要：

  Some new o-carborane derivatives of stoichiometry 1,2-(SR)(2)-1,2-C2B10H10 [SR=S2NC7H4, S2CNEt2] have been synthesised by reaction of 1,2-Li-2-1,2-C2B10H10 with the corresponding disulfide derivatives RSSR (RSSR=(C7H4NS2)(2), 2,2'-dithiobis(benzothiazole); (Et,NCS,), tetraethylthiuram disulfide) in molar ratio 1:2. The reaction of 1-Li-2-(SiBuMe2)-Bu-t-1,2-C2B10H10 with RSSR (RSSR= (C5H4NS)(2), 2,2'-dithiodipyridine; (C7H4NS2)(2)) in molar ratio 1:1 has afforded the new mixed di-substituted compounds 1-SR-2-(SiBuMe2)-Bu-t-1,2-C2B10H10 (SR=SNC5H4; S2NC7H4). The reaction of 1-SNC5H4-2-(SiBuMe2)-Bu-t- 1,2-C2B10H10 with NBu4F in THF in molar ratio 1:2 has afforded the mono-substituted derivative 1-SNC5H4-1,2-C2B10H10, whereas the treatment of 1,2-(C7H4NS2)(2)-1,2-C2B10H10 with NBu4F in THF in molar ratio 1:5 has led to the partially degraded derivative NBu4[7,8-(S2NC7H4)(2)-7,8-C2B9H10]. The crystal structure of 1-SNC5H4-1,2-C2B10H11 has been determined by X-ray diffraction. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00430-6