(phthalocyaninato)NbCl2 | 81780-16-7

• 英文名称: (phthalocyaninato)NbCl2
• 英文别名: dichloro(phthalocyaninate)niobium(IV)
• CAS: 81780-16-7
• 化学式: C₃₂H₁₆Cl₂N₈Nb
• 分子量: 676.345
• InChiKey: WWAUEIAYAQXZIS-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  disodium phthalocyanine 、 (phthalocyaninato)NbCl2 以 further solvent(s) 为溶剂， 以13%的产率得到bis(phthalocyaninate)niobium(IV) * 1-chloronaphthalene
  参考文献：
  名称：

  One Step Forward to “Stapled” Bis(phthalocyanine) Metal Complexes:  Synthesis, Characterization, and Redox Properties of Bis(phthalocyaninato)niobium(IV). X-ray Crystal Structure of the Monoelectronically Oxidized Species [Pc₂Nb](I₃)(I₂)_0.5(ClNP)_3.5 (ClNP = 1-Chloronaphthalene)

  摘要：

  Bis(phthalocyaninato)niobium(IV) has been prepared and isolated as a monosolvate, [Pc2Nb]. CINP (CINP = 1-chloronaphthalene). It is a light-brown, stable-to-air Nb(IV) (d(1)) paramagnetic sandwich-like species, which, upon oxidation by It under mild conditions, undergoes a metal-centered monoelectronic oxidation to give the diamagnetic Nb(V) (d(0)) [PC2Nb](+) fragment, with formation of saltlike species of formula [Pc2Nb](I-3)(I-2)0.5(CINP)(3.5) (I). The structure of I has been elucidated by single-crystal X-ray work. Crystals are triclinic: formula C64H32N16Nb . I-3 . 0.5I(2) . 3.5C(10)H(7)Cl, M = 2194.8, a = 17.702(3) Angstrom, b = 18.708(3) Angstrom, c = 13.504(2)Angstrom, V = 4267.5(13) Angstrom(3), alpha = 106.00(2)degrees, beta = 93.39(2)degrees, gamma = 83.26(1)degrees, Z = 2, space group P (1) over bar. The structure of the [Pc2Nb](+) fragment, "stapled" by two inter-ligand C-C sigma bonds (C11A-C11B and C31A-C31B = 1.574(15) Angstrom), together with its color and UV-visible spectral behavior, allows a straightforward assignment of the same "stapled" structure to the unoxidized [Pc2Nb]. The present niobium sandwiched materials reiterate the peculiar structural findings shown only by the previously reported [Pc2Ti].

  DOI：

  10.1021/ic970841f

文献信息

• Bis(phthalocyaninato)niobium(IV): a new sandwich-type molecule ‘stapled’ by two inter-ligand CC σ bonds
  作者：M.P. Donzello、C. Ercolani、P.J. Lukes

  DOI：10.1016/s0020-1693(97)05474-1

  日期：1997.3

  Bis(phthalocyaninato)niobium(IV), [Pc2Nb], a new sandwich-type molecule of unusual light-brown colour, has been obtained from the reaction of PcNbCl2 with PcNa2 in alpha-chloronaphthalene. Information at hand, including IR and UV-Vis spectral data, strongly suggests the presence in the complex of highly distorted Pc fragments 'stapled' by interligand C-C sigma bonds, a peculiar feature so far observed only in its Ti(IV) analogue, [Pc2Ti].