[Fe2(η5-C5H5)2(μ-κ1:κ1,η1-CyPCH2CH(CO2Me)C(O))(μ-CO)(CO)] | 869803-08-7

• 英文名称: [Fe2(η5-C5H5)2(μ-κ1:κ1,η1-CyPCH2CH(CO2Me)C(O))(μ-CO)(CO)]
• CAS: 869803-08-7
• 化学式: C₂₃H₂₇Fe₂O₅P
• 分子量: 526.132
• InChiKey: QGSFYSXREKPKSQ-HVWIKTGPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氟硼酸-二乙醚络合物 、 [Fe2(η5-C5H5)2(μ-κ1:κ1,η1-CyPCH2CH(CO2Me)C(O))(μ-CO)(CO)] 以 not given 为溶剂， 生成 [Fe2(η5-C5H5)2(μ-P(CH2CH2CO2Me)Cy)(μ-CO)(CO)2]BF4
  参考文献：
  名称：

  High-Yield Synthesis and Reactivity of Stable Diiron Complexes with Bent-Phosphinidene Bridges

  摘要：

  Reaction of [Fe2Cp2(mu-CO)(2)(CO)(PRH2)] (Cp = eta(5)-C5H5; R = Cy, Ph) with [FeCp2]BF4 gives the phosphide-bridged complexes [Fe2Cp2(mu-PRH)(mu-CO)(CO)(2)]BF4, which are deprotonated by M(OH) (M = Na, K) to give the phosphinidene derivatives [Fe2Cp2(mu-PR)(mu-CO)(CO)(2)] in high yield. The cyclohexylphosphinidene complex reacts at room temperature with MeI, O-2, S-8, or H2C=CHR' (R' = CO2Me) to give selectively [Fe2Cp2(mu-PCyMe)(mu-CO)(CO)(2)]I or neutral derivatives of the types [Fe2Cp2{mu-PCyMe)(mu-CO)(CO)(2)] (E = O, S) and [Fe2Cp2{mu-k(1):k(1), eta(1)-CyPCH2CHR'C(O)}(mu-CO)(CO)].

  DOI：

  10.1021/om050617v
• 作为产物：
  描述：

  [Fe2Cp2(μ-PCy)(μ-CO)(CO)2] 、 丙烯酸甲酯（MA） 以 not given 为溶剂， 生成 [Fe2(η5-C5H5)2(μ-κ1:κ1,η1-CyPCH2CH(CO2Me)C(O))(μ-CO)(CO)]
  参考文献：
  名称：

  High-Yield Synthesis and Reactivity of Stable Diiron Complexes with Bent-Phosphinidene Bridges

  摘要：

  Reaction of [Fe2Cp2(mu-CO)(2)(CO)(PRH2)] (Cp = eta(5)-C5H5; R = Cy, Ph) with [FeCp2]BF4 gives the phosphide-bridged complexes [Fe2Cp2(mu-PRH)(mu-CO)(CO)(2)]BF4, which are deprotonated by M(OH) (M = Na, K) to give the phosphinidene derivatives [Fe2Cp2(mu-PR)(mu-CO)(CO)(2)] in high yield. The cyclohexylphosphinidene complex reacts at room temperature with MeI, O-2, S-8, or H2C=CHR' (R' = CO2Me) to give selectively [Fe2Cp2(mu-PCyMe)(mu-CO)(CO)(2)]I or neutral derivatives of the types [Fe2Cp2{mu-PCyMe)(mu-CO)(CO)(2)] (E = O, S) and [Fe2Cp2{mu-k(1):k(1), eta(1)-CyPCH2CHR'C(O)}(mu-CO)(CO)].

  DOI：

  10.1021/om050617v