tricarbonyl(trifluoromethyl)(triphenylphosphine)cobalt | 14931-55-6

• 英文名称: tricarbonyl(trifluoromethyl)(triphenylphosphine)cobalt
• CAS: 14931-55-6
• 化学式: C₂₂H₁₅CoF₃O₃P
• 分子量: 474.321
• InChiKey: DEAOTTPEUDGDAD-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  以 四氢呋喃 为溶剂， 生成 tricarbonyl(trifluoromethyl)(triphenylphosphine)cobalt
  参考文献：
  名称：

  Tricarbonyl(trifluoromethyl)(triphenylphosphine)cobalt

  摘要：

  The title compound, [Co(CF3)(C18H15P)(CO)(3)], has a trigonal bipyramidal geometry with the trifluoromethyl and triphenylphosphine ligands occupying the trans-axial positions, The three carbonyl ligands occupy the planar equatorial positions. Both the trifluoromethyl and triphenylphosphine ligands are in a staggered conformation relative to the carbonyl ligands in the equatorial plane, The structure of the title compound is similar to other alkylcobalt tricarbonyl triphenylphosphines. Important bond distances include Co-CF3 1.953(6), Co-P1 2.235 (1), mean Co-CO 1.752 and mean P1-C 1.822 Angstrom.

  DOI：

  10.1107/s0108270196015910