[ruthenium(II)(H)(carbonyl)(triphenylphosphine)2(4-mercapto-5-phenyl-1,2-dithiole-3-thione(-H))] | 1206555-14-7

• 英文名称: [ruthenium(II)(H)(carbonyl)(triphenylphosphine)2(4-mercapto-5-phenyl-1,2-dithiole-3-thione(-H))]
• CAS: 1206555-14-7
• 化学式: C₄₆H₃₆OP₂RuS₄
• 分子量: 896.073
• InChiKey: MGMXLGOUZZBOPJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [RuHCl(CO)(PPh₃)₃] 、 5-phenyl-4-mercapto-1,2-dithiole-3-thione 在 NEt₃ 作用下， 以 四氢呋喃 为溶剂， 以93%的产率得到[ruthenium(II)(H)(carbonyl)(triphenylphosphine)2(4-mercapto-5-phenyl-1,2-dithiole-3-thione(-H))]
  参考文献：
  名称：

  Coordination of 4-mercapto-1,2-dithiole-3-thione heterocycles to ruthenium(II) and molybdenum(VI) centres

  摘要：

  Deprotonation of 4-mercapto-1,2-dithiole-3-thiones with NEt3 followed by reaction with [Ru(H)(Cl)-(CO)(PPh3)(3)] affords virtually quantitative yields of turquoise [Ru(H)(RC3S4)(CO)(PPh3)(2)] (R = Ph, Mes) in which the heterocycle is bound as a bidentate uninegative ligand through the two exocyclic sulfur atoms. The presence of both possible isomers in each case is indicated by NMR spectroscopy. Reaction of the 4-mercapto-1,2-dithiole-3-thiones with [MoO2(acac)(2)] results in displacement of the acac ligands and formation of [MoO2(RC3S4)(2)]. The crystal structures of [Ru(H)(MesC(3)S(4))(CO)(PPh3)(2)] and [MoO2-(MesC(3)S(4))(2)] have been determined. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.09.015