[μ,η(2)-C(O)N(i)Pr2]2Fe2(CO)6 | 247102-66-5

• 英文名称: [μ,η(2)-C(O)N(i)Pr2]2Fe2(CO)6
• CAS: 247102-66-5
• 化学式: C₂₀H₂₈Fe₂N₂O₈
• 分子量: 536.145
• InChiKey: BUHIHBUCAJACEO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  正丁基锂 、 草酰氯 、 五羰基铁 、 二异丙胺 以 四氢呋喃 、 正己烷 为溶剂， 以72%的产率得到[μ,η(2)-C(O)N(i)Pr2]2Fe2(CO)6
  参考文献：
  名称：

  Synthesis of bis-(acyl, carbamoyl or alkoxycarbonyl) iron monomer or dimer complexes by reaction of oxalyl chloride with various tetracarbonyl ferrates: {Fe[C(O)R](CO)4}−

  摘要：

  The reaction of oxalyl chloride with various tetracarbonyl ferrates bearing a carbonylated organic ligand induces the formation of bis substituted monomers Fe[C(O)R](2)(CO)(4) or dimers (Fe[C(O)R](CO)(4))(2) and of bis-[mu,eta(2)-C(O)R]Fe-2(CO)(6) bridged dimers. The orientation of the reaction depends on the nature of the organic ligand of the ferrates. Thus carbamoyls or alkoxycarbonyls ferrates bearing mobile R groups are found to induce the formation of bis substituted monomers while bulky alkoxycarbonyl ligands afford non-bridged dimers. Acyls and bulky carbamoyls give rise to dimers bearing bridging acyls or carbamoyls. The mechanisms of formation of these different complexes and the possible thermal interconversions of these compounds are investigated. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00024-9