1-ethyl-6,7-bis(η(5)-pentamethylcyclopentadienyl)-closo-1,6,7-azadirhodadecaborane(7) | 189037-59-0

• 英文名称: 1-ethyl-6,7-bis(η(5)-pentamethylcyclopentadienyl)-closo-1,6,7-azadirhodadecaborane(7)
• CAS: 189037-59-0
• 化学式: C₂₂H₄₂B₇NRh₂
• 分子量: 602.07
• InChiKey: YLQXCIHVRGFYGZ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Rh(pentamethylcyclopentadienyl)Cl2]2 、 在 NaH 作用下， 以 四氢呋喃 为溶剂， 以6%的产率得到1-ethyl-6,7-bis(η(5)-pentamethylcyclopentadienyl)-closo-1,6,7-azadirhodadecaborane(7)
  参考文献：
  名称：

  Polyhedral azadirhodaborane chemistry. Reaction of [{RhCl2(η5-C5Me5) }2] with [EtH2NB8H11NHEt] to give contiguous ten-vertex [1-Et-6,7-(η5-C5Me5)2- closo-6,7,1-Rh2NB7H7 ]

  摘要：

  The novel monoazadirhodaborane [1-Et-6,7-(η 5 -C 5 Me 5 ) 2 - closo-1,6,7-NRh 2 B 7 H 7 ], of ten-vertex stretched closo-type geometry, has been isolated in 6% yield from the reaction in tetrahydrofuran between [{RhCl 2 (η 5 -C 5 Me 5 ) } 2 ], NaH and [EtH 2 NB 8 H 11 NHEt]; the latter azaborane compound therefore exhibits good augury as a potentially interesting and useful azametallaborane synthon.

  DOI：

  10.1039/a700132k