(Me2Si(Cp(t-Bu))2)YCH2TMS*THF | 214214-77-4

• 英文名称: (Me2Si(Cp(t-Bu))2)YCH2TMS*THF
• CAS: 214214-77-4
• 化学式: C₂₈H₄₉OSi₂Y
• 分子量: 546.773
• InChiKey: JFCDGKKJJRAJHW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Li2[Me2Si(Cp(t-Bu))2] 、 yttrium trichloride*3tetrahydrofuran 、 trimethylsilylmethyllithium 以 甲苯 、 正戊烷 为溶剂， 以20%的产率得到(Me2Si(Cp(t-Bu))2)YCH2TMS*THF
  参考文献：
  名称：

  Investigation of the Regioselectivity of Alkene Hydrosilylation Catalyzed by Organolanthanide and Group 3 Metallocene Complexes

  摘要：

  The regioselectivity of monosubstituted alkene hydrosilylation catalyzed by organolanthanide and group 3 organometallic complexes has been studied as a function of catalyst structure. A wide variety of catalyst variations were shown to be compatible with the hydrosilylation process. Several novel complexes were synthesized to widen the scope of this investigation. The results show complexes containing larger lanthanide metal ions and reduced substitution on the cyclopentadienyl ligands produce increased yields of the secondary silane product. Several complexes were identified that are highly selective for primary silane generation.

  DOI：

  10.1021/om980279g