2,6-diacetylpyridinebis(phenylthiosemicarbazone)(chloro)(methanol)iron(II) chloride | 1144507-28-7

• 英文名称: 2,6-diacetylpyridinebis(phenylthiosemicarbazone)(chloro)(methanol)iron(II) chloride
• CAS: 1144507-28-7
• 化学式: C₂₄H₂₇ClFeN₇OS₂*Cl
• 分子量: 620.41
• InChiKey: UHTXNOIKQQBKRL-YCVYWETJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,6-diacetylpyridinebis(phenylthiosemicarbazone) 、 三氯化铁 以 甲醇 为溶剂， 以70%的产率得到2,6-diacetylpyridinebis(phenylthiosemicarbazone)(chloro)(methanol)iron(II) chloride
  参考文献：
  名称：

  Iron and cobalt complexes of 2,6-diacetylpyridine-bis(R-thiosemicarbazone) (R=H, phenyl) showing unprecedented ligand deviation from planarity

  摘要：

  The syntheses, characterization, and single-crystal X-ray crystal structures are reported for four complexes of iron and cobalt with the pentadentate ligands, 2,6-diacetylpyridinebis(thiosemicarbazone) (H2L1) and 2,6-diacetylpyridinebis(phenylthiosemicarbazone) (H2L2), including a cobalt dimer displaying a deviation from planarity which is unprecedented for this class of ligands and allows the ligand to occupy five positions of a pseudo-octahedral coordination sphere. This dimer reacts with KCN to produce a mononuclear complex of relevance to the active site of cobalt nitrile hydratase. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.06.031