Fc(CH2)11OC6H4OH | 1100051-56-6

• 英文名称: Fc(CH2)11OC6H4OH
• CAS: 1100051-56-6
• 化学式: C₂₇H₃₆FeO₂
• 分子量: 448.429
• InChiKey: IWKHOGYEGOTIAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Fc(CH2)11OC6H4OH 以 not given 为溶剂， 生成 ([(η5-C5H5)Fe(η5-C5H4)]3Si(CH2)2)5H3Si8O12
  参考文献：
  名称：

  巨型烷基二茂铁基树枝状大分子在氧阴离子识别中的树枝状和离子对作用

  摘要：

  含有3个树枝状聚合物Ñ 2长系绳（Ñ =生成编号从0到7：G ^ 0 -G 7）由alkylferrocenyl末端终止被用于氧化还原识别含氧阴离子h的2 PO 4 -和ATP 2-通过循环伏安法（CV），以研究在不存在与二茂铁基末端连接的官能团的情况下的离子对和树突作用。由于它们与扰动二茂铁基电位的阴离子的超分子相互作用，以前假定这些基团在氧化还原识别的大小中起重要作用。CH 2 Cl 2中的滴定这些金属树状聚合物与氧代阴离子的n -Bu 4 N +盐溶液以较低的正电势提供了新的CV波，而初始二茂铁基CV波的强度降低了。而二茂铁和所述参考单金属化合物的Fc（CH 2）11 OC 6 H ^ 4 OH，1（FC =二茂铁基），经历用H仅可逆的离子配对相互作用2 PO 4 - ，氧代-阴离子的反应与二茂铁基树枝状聚合物快速而完整（每个二茂铁基支链上有1个当量的氧阴离子）。波电位差ΔE 1/2

  DOI：

  10.1021/om900277u
• 作为产物：
  描述：

  11-bromo-n-undecylferrocene 、 对苯二酚 在 potassium carbonate 、 sodium iodide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 Fc(CH2)11OC6H4OH
  参考文献：
  名称：

  Giant Dendritic Molecular Electrochrome Batteries with Ferrocenyl and Pentamethylferrocenyl Termini

  摘要：

  Giant redox dendrimers were synthesized with ferrocenyl and pentamethylferrocenyl termini up to a theoretical number of 39 tethers (seventh generation). Lengthening of the tethers proved to be a reliable strategy to overcome the bulk constraint at the dendrimers periphery. These redox metallodendrimers were characterized by H-1, C-13, and Si-29 NMR; MALDI-TOF mass spectrometry (for the low generations); elemental analysis; UV-vis spectroscopy; dynamic light scattering (DLS); atomic force microscopy (AFM); electron-force microscopy (EFM) for hall- or fully oxidized dendrimers; cyclic voltammetry; and coulometry. UV-vis spectroscopy, coulometry, and analytical data are consistent with an increasing amount of defects as the generation number increases, with this amount remaining relatively weak up to G(5). AFM shows that the dendrimers form aggregates of discrete size on the mica surface, recalling the agglomeration of metal atoms in monodisperse nanoparticles. Cyclic voltarnmetry reveals full chemical and electrochemical reversibility up to G(7), showing that electron transfer is fast among the flexible peripheral redox sites. Indeed, the redox stability of these new electrochromic dendrimers, i.e., a battery behavior, was established by complete chemical oxido-reduction cycles, and the blue 17-electron ferrocenium and deep-green mixed-valence Fe(III)/Fe(II) dendritic complexes were isolated and characterized. AFM studies also show the reversible dendrimer size changes from upon redox switching between Fe(II) and Fe(III), suggesting a breathing mechanism controlled by the redox potential. Considerable adsorption of high-generation dendrimers on Pt electrodes such as G(7)-Fc allows the easy formation of modified electrodes that sense the ATP anion only involving the electrostatic factor even in the absence of any other type of interaction with the redox tethers.

  DOI：

  10.1021/ja8062343